Removal of impurities from scandium chloride solution using 732-type resin
来源期刊：JOURNAL OF RARE EARTHS2018年第3期
论文作者：Guotao Zhou Qinggang Li Pan Sun Wenjuan Guan Guiqing Zhang Zuoying Cao Li Zeng
文章页码：311 - 316
摘 要：The deep removal of Al, Fe（Ⅱ/Ⅲ）, Ca, Zr, Ti and Si from scandium chloride solution was carried out by using 732-type strong acid cation exchange resin. The effects of pH value, contact time and complexing agents（EDTA） on the purification process are investigated. The results indicate that the 732-type resin have a good scandium selectivity and the adsorption order is Sc > Fe（Ⅲ）>Al > Ca > Zr > Ti > Si in the pH range of 1-3. The separation of Sc and Zr, Si, Ti can be directly carried out because the resin have a good adsorption effect on Sc, AI and Fe（Ⅲ） but poor adsorption effect on Zr, Si and Ti under the condition of pH = 2.5 and contact time 180 min. The Fe（Ⅱ）, Ca and Al are selectively adsorbed on the resin by adding reducing agent ascorbic acid and EDTA into the solution for reducing Fe（Ⅲ） to Fe（Ⅱ） and complexing Sc.By using two-step ion exchange adsorption separation method, the removal rates of Fe（Ⅲ）, Ti, Al, Ca, Zr and Si are 95.5%,99.8%,100%,98.2%,98.6% and 100%,respectively.
Guotao Zhou1,2，Qinggang Li1,2，Pan Sun1,2，Wenjuan Guan1,2，Guiqing Zhang1,2，Zuoying Cao1,2，Li Zeng1,2
1. School of Metallurgy and Environment,Central South University2. Key Laboratory of Hunan Province for Metallurgy and Material Processing of Rare Metals
摘 要：The deep removal of Al, Fe（Ⅱ/Ⅲ）, Ca, Zr, Ti and Si from scandium chloride solution was carried out by using 732-type strong acid cation exchange resin. The effects of pH value, contact time and complexing agents（EDTA） on the purification process are investigated. The results indicate that the 732-type resin have a good scandium selectivity and the adsorption order is Sc > Fe（Ⅲ）>Al > Ca > Zr > Ti > Si in the pH range of 1-3. The separation of Sc and Zr, Si, Ti can be directly carried out because the resin have a good adsorption effect on Sc, AI and Fe（Ⅲ） but poor adsorption effect on Zr, Si and Ti under the condition of pH = 2.5 and contact time 180 min. The Fe（Ⅱ）, Ca and Al are selectively adsorbed on the resin by adding reducing agent ascorbic acid and EDTA into the solution for reducing Fe（Ⅲ） to Fe（Ⅱ） and complexing Sc.By using two-step ion exchange adsorption separation method, the removal rates of Fe（Ⅲ）, Ti, Al, Ca, Zr and Si are 95.5%,99.8%,100%,98.2%,98.6% and 100%,respectively.
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