SrAl2O4∶Eu2+, Nd3+ and Dy3+ Long Afterglow Phosphor
来源期刊：JOURNAL OF RARE EARTHS2003年第2期
论文作者：何大伟 崔兴龙 吕菁华
Key words：optics; long afterglow phosphor; SrAl2O4∶Eu2+,Dy3+; trapping centers; rare earths;
Abstract: The SrAl2O4∶Eu2+, Nd3+ and SrAl2O4∶Eu2+, Dy3+ long afterglow phosphor were synthesized. Their excitation and emission spectra at different excitation and afterglow characteristics were analyzed after the excitation power was taken off. The effects of Eu2+, Dy3+, Nd3+ mole concentrations on phosphorescence characteristics were also discussed. It is crucial to have trapping levels located at a suitable depth related to the thermal release rate at room temperature. The incorporation of Nd3+ ions as an auxiliary activator into the SrAl2O4∶Eu2+ system causes very intense and long phosphorescence. The response time of SrAl2O4∶Eu2+, Dy3+ phosphors is quicker than that of SrAl2O4∶Eu2+, Nd3+. Phosphorescence characteristics of SrAl2O4∶Eu2+, Nd3+ is much better than those of SrAl2O4∶Eu2+, Dy3+. The integrate area of the excitation spectrum of SrAl2O4∶Eu2+, Nd3+ phosphor is larger than that of SrAl2O4∶Eu2+, Dy3+ phosphor within the range of 250～360 nm. For phosphorescence characteristics to the system of SrAl2O4∶Eu2+, Nd3+ phosphor, the optimum concentration of Nd3+ trivalent rare earth ions is 0.05 mol.
何大伟1，崔兴龙1，吕菁华2
(1.Ministry of Education Key Laboratory, Labatory of Materials for Information Storage and Display Institute of Photo-Electronic Technology Northern Jiaotong University, Beijing 100044, China;
2.Hulan Branch, Harbin Normal University, Harbin 150500, China)
Abstract:The SrAl2O4∶Eu2+, Nd3+ and SrAl2O4∶Eu2+, Dy3+ long afterglow phosphor were synthesized. Their excitation and emission spectra at different excitation and afterglow characteristics were analyzed after the excitation power was taken off. The effects of Eu2+, Dy3+, Nd3+ mole concentrations on phosphorescence characteristics were also discussed. It is crucial to have trapping levels located at a suitable depth related to the thermal release rate at room temperature. The incorporation of Nd3+ ions as an auxiliary activator into the SrAl2O4∶Eu2+ system causes very intense and long phosphorescence. The response time of SrAl2O4∶Eu2+, Dy3+ phosphors is quicker than that of SrAl2O4∶Eu2+, Nd3+. Phosphorescence characteristics of SrAl2O4∶Eu2+, Nd3+ is much better than those of SrAl2O4∶Eu2+, Dy3+. The integrate area of the excitation spectrum of SrAl2O4∶Eu2+, Nd3+ phosphor is larger than that of SrAl2O4∶Eu2+, Dy3+ phosphor within the range of 250～360 nm. For phosphorescence characteristics to the system of SrAl2O4∶Eu2+, Nd3+ phosphor, the optimum concentration of Nd3+ trivalent rare earth ions is 0.05 mol.
Key words:optics; long afterglow phosphor; SrAl2O4∶Eu2+,Dy3+; trapping centers; rare earths;
【全文内容正在添加中】
