Synthesis and Luminescent Properties of Terbium Complexes with Acrylonitrile-co-styrene
来源期刊：Journal of Rare Earths2006年第S2期
论文作者：郭栋才
文章页码：1 - 6
摘 要：Eight terbium complexes with aromatic carboxylic acid and acrylonitrile-co-styrene were fabricated by means of method from coordination to polymerization; and characterized by means of FT-IR and UV spectra analysis. Their thermal and luminescent properties were also investigated with thermal analysis and fluorescence spectra instruments, respectively. The results show that all terbium macro-molecule complexes possess nice thermal and luminescent properties. After terbium complexes ligands polymerized styrene, the change of molecule structures caused the energy transfer efficiency of ligands to change, and led to the luminescent intensity sequence of terbium complexes with aromatic carboxylic acid and acrylonitrile-co-styrene to be different from that of terbium complexes ligands.
郭栋才1
1. School of Chemistry and Chemical Engineering, Hunan University
摘 要：Eight terbium complexes with aromatic carboxylic acid and acrylonitrile-co-styrene were fabricated by means of method from coordination to polymerization; and characterized by means of FT-IR and UV spectra analysis. Their thermal and luminescent properties were also investigated with thermal analysis and fluorescence spectra instruments, respectively. The results show that all terbium macro-molecule complexes possess nice thermal and luminescent properties. After terbium complexes ligands polymerized styrene, the change of molecule structures caused the energy transfer efficiency of ligands to change, and led to the luminescent intensity sequence of terbium complexes with aromatic carboxylic acid and acrylonitrile-co-styrene to be different from that of terbium complexes ligands.
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