简介概要

The Double-Double Effect of Lanthanide Complexes with Styrene-Acrylic Acid Copolymer

来源期刊:Journal of Rare Earths1992年第2期

论文作者:于广谦 李玉良 刘丛明

文章页码:148 - 150

摘    要:<正> The double-double (or tetrad) effect of low molecular lanthanide complexes has been reportedsince the effect was discovered by Fidelis and Siekierski.However,so far no description concerning thedouble-double effect of macromolecular lanthanide complexes has been published in literature.We have been successful in preparing lanthanide complexes with styrene-acrylic acid copolymer,someof which exhibite high activitiest in butadiene polymerization.It was found that the complexes showedthe double-double effect as they were characterized.In the present paper,the SAAC·Ln IR spectra whichcharacterize the double-double effect have been discussed in detail.

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The Double-Double Effect of Lanthanide Complexes with Styrene-Acrylic Acid Copolymer

于广谦,李玉良,刘丛明

摘 要:<正> The double-double (or tetrad) effect of low molecular lanthanide complexes has been reportedsince the effect was discovered by Fidelis and Siekierski.However,so far no description concerning thedouble-double effect of macromolecular lanthanide complexes has been published in literature.We have been successful in preparing lanthanide complexes with styrene-acrylic acid copolymer,someof which exhibite high activitiest in butadiene polymerization.It was found that the complexes showedthe double-double effect as they were characterized.In the present paper,the SAAC·Ln IR spectra whichcharacterize the double-double effect have been discussed in detail.

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