Synthesis and Luminescence Properties of Red Phosphors:Mn2+ Doped MgSiO3 and Mg2SiO4 Prepared by Sol-Gel Method
来源期刊：JOURNAL OF RARE EARTHS2006年增刊第2期
论文作者：Shi Chaoshu Zhang Weiping You Baogui
Key words：manganese; magnesium silicate; orthosilicate; red long-lasting phosphor; rare earths;
Abstract: Sol-gel method was utilized to synthesize two different series of red silicate phosphors:MgSiO3 and Mg2SiO4 powder samples doped with Mn2+, conducted the investigation of red long-lasting phosphor: MgSiO3:Eu2+, Dy3+, Mn2+. TGA curves of the gel precursor for two series depicted that the loss of residual organic groups and NO3 groups occurs below 450 ℃. According to the XRD patterns, the major diffraction peaks of the MgSiO3 and Mg2SiO4 series are consistent with a proto-enstatite structure (JCPDS No.11-0273) and a forsterite structure (JCPDS No.85-1364) respectively. With the excitation at 415 nm, the red emission band of Mn2+ ions is peaked at 661 nm for MgSiO3:1%(atom fraction) Mn2+ or 644 nm for Mg2SiO4:1%(atom fraction) Mn2+. Compared with Mg2SiO4:Mn2+ samples, MgSiO3:Mn2+ samples exhibit higher luminescence intensity and higher quenching concentration. In addition, the two series co-doped with Eu2+, Dy3+, Mn2+ were also prepared. Photo-luminescence and afterglow properties of the two co-doped series were analyzed, which show that MgSiO3:Eu2+, Dy3+, Mn2+ is more suitable for a red long-lasting phosphor.
Shi Chaoshu1，Zhang Weiping1，Lin Lin2，You Baogui1，Yin Min2
(1.Physics Department, University of Science and Technology of China, Hefei 230026, China;
2.Structure Research Laboratory, University of Science and Technology of China, Chinese Academy of Sciences, Hefei 230026, China)
Abstract:Sol-gel method was utilized to synthesize two different series of red silicate phosphors:MgSiO3 and Mg2SiO4 powder samples doped with Mn2+, conducted the investigation of red long-lasting phosphor: MgSiO3:Eu2+, Dy3+, Mn2+. TGA curves of the gel precursor for two series depicted that the loss of residual organic groups and NO3 groups occurs below 450 ℃. According to the XRD patterns, the major diffraction peaks of the MgSiO3 and Mg2SiO4 series are consistent with a proto-enstatite structure (JCPDS No.11-0273) and a forsterite structure (JCPDS No.85-1364) respectively. With the excitation at 415 nm, the red emission band of Mn2+ ions is peaked at 661 nm for MgSiO3:1%(atom fraction) Mn2+ or 644 nm for Mg2SiO4:1%(atom fraction) Mn2+. Compared with Mg2SiO4:Mn2+ samples, MgSiO3:Mn2+ samples exhibit higher luminescence intensity and higher quenching concentration. In addition, the two series co-doped with Eu2+, Dy3+, Mn2+ were also prepared. Photo-luminescence and afterglow properties of the two co-doped series were analyzed, which show that MgSiO3:Eu2+, Dy3+, Mn2+ is more suitable for a red long-lasting phosphor.
Key words:manganese; magnesium silicate; orthosilicate; red long-lasting phosphor; rare earths;
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