Preparation of Sr2Fe1-xScxMoO6-δ nanopowders and its electrical conductivity
来源期刊：Journal of Rare Earths2011年第7期
论文作者：葛奔 艾德生 马景陶 邓长生 林旭平
文章页码：673 - 677
摘 要：Double-perovskite Sr2Fe1-xScxMoO6-δ （x=0, 0.05, 0.1, 0.2, 0.3, 0.4） powders applied to the cathode of solid oxide electrolysis cells were synthesized by the sol-gel citrate combustion method. Initial powders were calcined at different temperatures under different atmosphere （air, H2（4 vol.%）/Ar）, and the effects of the preparation process on the structure and the morphology of the powders were investigated by thermal analysis （TG/DSC）, X-ray diffraction （XRD）, scanning electron microscopy （SEM） and surface area analysis. The electric conductiv-ity of the materials was measured by electrochemical work station using wafers prepared by dry pressing. It was found that the formation of perovskite structure was related to the content of Sc and combustion improver （NH4NO3）, pH value, calcining temperature and atmosphere. A single perovskite phase of Sr2Fe1-xScxMoO6-δ could be formed after 3 h calcining in reducing atmosphere of H2 （4 vol.%）/Ar at 1100 oC. The electrical property indicated that, this material had a potential to be used in medium/high temperature solid oxide fuel cells or electrolysis cells.
葛奔，艾德生，马景陶，邓长生，林旭平
State Key Laboratory of New Ceramics and Fine Processing, Beijing Key Lab of Fine Ceramics, Institute of Nuclear and New Energy Technology, Tsinghua University
摘 要：Double-perovskite Sr2Fe1-xScxMoO6-δ （x=0, 0.05, 0.1, 0.2, 0.3, 0.4） powders applied to the cathode of solid oxide electrolysis cells were synthesized by the sol-gel citrate combustion method. Initial powders were calcined at different temperatures under different atmosphere （air, H2（4 vol.%）/Ar）, and the effects of the preparation process on the structure and the morphology of the powders were investigated by thermal analysis （TG/DSC）, X-ray diffraction （XRD）, scanning electron microscopy （SEM） and surface area analysis. The electric conductiv-ity of the materials was measured by electrochemical work station using wafers prepared by dry pressing. It was found that the formation of perovskite structure was related to the content of Sc and combustion improver （NH4NO3）, pH value, calcining temperature and atmosphere. A single perovskite phase of Sr2Fe1-xScxMoO6-δ could be formed after 3 h calcining in reducing atmosphere of H2 （4 vol.%）/Ar at 1100 oC. The electrical property indicated that, this material had a potential to be used in medium/high temperature solid oxide fuel cells or electrolysis cells.
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