Experimental investigation on phase equilibria of Ce-Sn-Zn system at 400 ℃
来源期刊：JOURNAL OF RARE EARTHS2012年第9期
论文作者：梁建烈 韩艳美 欧阳义芳 谢世标 蒙洁丽 朱立炫 零妙然
文章页码：916 - 922
摘 要：The Ce-Sn-Zn alloys were prepared by furnace melting. The isothermal section of the Ce-Sn-Zn system at 400 oC over the whole composition range was established by using X-ray diffraction （XRD）, scanning electron microscopy （SEM） and energy dispersive spectrometry （EDS）. A new ternary compound, CeSn 2 Zn 2 , was discovered in the present work. This compound adopted CaBe 2 Ge 2 structure type （space group P4/nmm） with the lattice parameters of a=0.4455 （9） nm and c=1.0348 （1） nm. The existence of previously known ternary compounds, CeSnZn and Ce 2 SnZn 3 , were confirmed, too. The maximum solubility of Zn in CeSn 3 was determined to be 12.7 at.%.
梁建烈1,2,3，韩艳美1,2，欧阳义芳2，谢世标1，蒙洁丽1，朱立炫1，零妙然1,2
1. Institute of Materials Science, College of Science, Guangxi University for Nationalities2. Department of Physics, Guangxi University3. Guangxi Key Laboratory of Hybrid Computational and IC Design Analysis
摘 要：The Ce-Sn-Zn alloys were prepared by furnace melting. The isothermal section of the Ce-Sn-Zn system at 400 oC over the whole composition range was established by using X-ray diffraction （XRD）, scanning electron microscopy （SEM） and energy dispersive spectrometry （EDS）. A new ternary compound, CeSn 2 Zn 2 , was discovered in the present work. This compound adopted CaBe 2 Ge 2 structure type （space group P4/nmm） with the lattice parameters of a=0.4455 （9） nm and c=1.0348 （1） nm. The existence of previously known ternary compounds, CeSnZn and Ce 2 SnZn 3 , were confirmed, too. The maximum solubility of Zn in CeSn 3 was determined to be 12.7 at.%.
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