Calorimetric Studies of the Synergistic Effect: The Reaction of RE（TTA）3 with N503 in Toluene
来源期刊：Journal of Rare Earths1991年第1期
论文作者：王文清 杨桦
文章页码：15 - 19
摘 要：<正> Titration calorimetry has been used to study the thermodynamics of reaction in toluene solution of2-thenoyltriflueroacetone（TTA）complexes of rare earths（RE=Y,Nd,Eu,Yb）with N,Ndimethylheptyl-acetamide（N503）at 298.15 K.The heat of the reaction was determined with a TRONACModel 1250 automatic isoperibol calorimeter.The data and figures of titration curve were recorded by the com-puter automatically.An iterative technique of least-square analysis was used to calculate the equilibrium con-stants and the thermodynamic functions including the entropy and free energy changes,minimizing the errorsquare sum by a computer program.
王文清，杨桦
摘 要：<正> Titration calorimetry has been used to study the thermodynamics of reaction in toluene solution of2-thenoyltriflueroacetone（TTA）complexes of rare earths（RE=Y,Nd,Eu,Yb）with N,Ndimethylheptyl-acetamide（N503）at 298.15 K.The heat of the reaction was determined with a TRONACModel 1250 automatic isoperibol calorimeter.The data and figures of titration curve were recorded by the com-puter automatically.An iterative technique of least-square analysis was used to calculate the equilibrium con-stants and the thermodynamic functions including the entropy and free energy changes,minimizing the errorsquare sum by a computer program.
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