Research on micro-structure and catalysis properties of nanosized Ce1–x(Fe0.5Eu0.5)xO2–δ solid solutions
来源期刊：Journal of Rare Earths2017年第1期
论文作者：张国芳 许剑轶 侯忠辉 王青春
文章页码：63 - 70
摘 要：Nanosized Fe3+ and Eu3+ codoped CeO2 solid solutions were synthesized via hydrothermal method. The crystalline structure of Ce1–x(Fe0.5Eu0.5)xO2–δ（x=0.00–0.30） solid solutions was carried out by the X-ray diffraction technique, and the spectrum features were identified by UV-Vis and Raman spectroscopy, respectively. It was observed that the cell parameters were first increased then decreased by increasing the doped ions content. The phase separation was detected when the dopant concentration reached to x=0.30. UV-Vis spectrum showed that the width of the band gap gradually reduced by increasing the doped content, and the solid solubility was determined to be x=0.20. The Raman technique displayed that the peak position of F2g mode gradually shifted to lower frequencies from 465 cm–1 for x=0.00 to 440 cm–1 for x=0.20. The catalytic effects of Ce1–x(Fe0.5Eu0.5)xO2–δ solid solutions on the electrochemistry properties of Mg2Ni/Ni were measured by mixing them together via ball milling technique. The electrochemical properties of the Mg2Ni/Ni-Ce1–x(Fe0.5Eu0.5)xO2–δ composites showed that the maximum discharge capability Cmax and the cycle stability were improved obviously. Meanwhile, the EIS characteristic also indicated that the doped solid solutions could enhance the rate of charge transfer on the surface of alloy. The catalytic effect of the solid solutions was speculated to rely on both the concentration of oxygen vacancies and the cell volumes of the solid solutions.
张国芳1,2，许剑轶1，侯忠辉1，王青春1
1. School of Material and Metallurgy,Inner Mongolia University of Science and Technology2. Key Laboratory of Intergrate Exploration of Baiyun Obo Multi-metal Resources,Inner Mongolia University of Science and Technology
摘 要：Nanosized Fe3+ and Eu3+ codoped CeO2 solid solutions were synthesized via hydrothermal method. The crystalline structure of Ce1–x(Fe0.5Eu0.5)xO2–δ（x=0.00–0.30） solid solutions was carried out by the X-ray diffraction technique, and the spectrum features were identified by UV-Vis and Raman spectroscopy, respectively. It was observed that the cell parameters were first increased then decreased by increasing the doped ions content. The phase separation was detected when the dopant concentration reached to x=0.30. UV-Vis spectrum showed that the width of the band gap gradually reduced by increasing the doped content, and the solid solubility was determined to be x=0.20. The Raman technique displayed that the peak position of F2g mode gradually shifted to lower frequencies from 465 cm–1 for x=0.00 to 440 cm–1 for x=0.20. The catalytic effects of Ce1–x(Fe0.5Eu0.5)xO2–δ solid solutions on the electrochemistry properties of Mg2Ni/Ni were measured by mixing them together via ball milling technique. The electrochemical properties of the Mg2Ni/Ni-Ce1–x(Fe0.5Eu0.5)xO2–δ composites showed that the maximum discharge capability Cmax and the cycle stability were improved obviously. Meanwhile, the EIS characteristic also indicated that the doped solid solutions could enhance the rate of charge transfer on the surface of alloy. The catalytic effect of the solid solutions was speculated to rely on both the concentration of oxygen vacancies and the cell volumes of the solid solutions.
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