Kinetics of nitric acid leaching of cerium from oxidation roasted Baotou mixed rare earth concentrate
来源期刊：JOURNAL OF RARE EARTHS2019年第2期
论文作者：Kai Li Ji Chen Dan Zou Tianchi Liu Deqian Li
文章页码：198 - 204
摘 要：The kinetics of nitric acid leaching of cerium was investigated for the oxidation roasted Baotou mixed rare earth concentrate. The effects of leaching temperature, HNO3 concentration, liquidesolid ratio（L/S）and stirring rate on rare earth extraction were studied. The XRD and SEM mapping analysis of the samples before and after acid leaching shows that the roasted bastnaesite is completely leached. Besides,the decomposition process of oxidizing roasting was also obtained by TGe MS and XRD. Different kinetics models were applied in this leaching process. The results of dynamic fitting show that the leaching process can be described by a new variant of the shrinking-core model. And the leaching rate is controlled by both the interfacial transfer and diffusion through the product layer. The apparent activation energy is calculated as 76.78 kJ/mol and the reaction orders with respect to HNO3 concentrations and liquidesolid ratio are determined to be 7.609 and 2.516, respectively. Besides, an empirical rate equation is obtained to describe the process.
Kai Li1,2，Ji Chen1，Dan Zou1，Tianchi Liu1,2，Deqian Li1
1. State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences2. University of Science and Technology of China
摘 要：The kinetics of nitric acid leaching of cerium was investigated for the oxidation roasted Baotou mixed rare earth concentrate. The effects of leaching temperature, HNO3 concentration, liquidesolid ratio（L/S）and stirring rate on rare earth extraction were studied. The XRD and SEM mapping analysis of the samples before and after acid leaching shows that the roasted bastnaesite is completely leached. Besides,the decomposition process of oxidizing roasting was also obtained by TGe MS and XRD. Different kinetics models were applied in this leaching process. The results of dynamic fitting show that the leaching process can be described by a new variant of the shrinking-core model. And the leaching rate is controlled by both the interfacial transfer and diffusion through the product layer. The apparent activation energy is calculated as 76.78 kJ/mol and the reaction orders with respect to HNO3 concentrations and liquidesolid ratio are determined to be 7.609 and 2.516, respectively. Besides, an empirical rate equation is obtained to describe the process.
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