Structure and spectral measurements of a new rubidium europium polyphosphate
来源期刊：Rare Metals2015年第12期
论文作者：Jing Zhu Hui Chen Yan Zheng Hui-Lan Kong Wen-Dan Cheng Yu-De Wang Hong-Tao Guan Zhong-Qi Zhu
文章页码：877 - 881
摘 要：A new rubidium europium polyphosphate,RbEu（PO3）4,was synthesized by the high-temperature solution reaction and studied by single-crystal X-ray diffraction（XRD） technique.RbEu（PO3）4 belongs to the monoclinic space group P21/n（Z = 4） and characterizes a three-dimensional framework made up from double PO4 spiral chains,RbO11,and EuO8 polyhedra.The absorption spectrum indicates that the compound has no absorption above 320 nm with insulator characteristic.In addition,the infrared spectroscopy was carried out.
Jing Zhu1，Hui Chen1，Yan Zheng1，Hui-Lan Kong1，Wen-Dan Cheng2，Yu-De Wang1，Hong-Tao Guan1，Zhong-Qi Zhu1
1. Department of Material Science and Engineering,Yunnan University2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences
摘 要：A new rubidium europium polyphosphate,RbEu（PO3）4,was synthesized by the high-temperature solution reaction and studied by single-crystal X-ray diffraction（XRD） technique.RbEu（PO3）4 belongs to the monoclinic space group P21/n（Z = 4） and characterizes a three-dimensional framework made up from double PO4 spiral chains,RbO11,and EuO8 polyhedra.The absorption spectrum indicates that the compound has no absorption above 320 nm with insulator characteristic.In addition,the infrared spectroscopy was carried out.
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