Upconversion photoluminescence properties of SrY2O4:Er3+,Yb3+ under 1550 and 980 nm excitation
来源期刊：Journal of Rare Earths2016年第5期
论文作者：沈显良 邢明铭 田莹 付姚 彭勇 罗昔贤
文章页码：458 - 463
摘 要：Er3+/Yb3+ co-doped SrY2O4 phosphors with high color purity and brightness were successfully synthesized via a solid-state reaction method.Luminescence spectrum studies showed that the main red peaks and the minor green peaks of upconversion emissions were located at approximately 634–681 nm and 543–570 nm,respectively,corresponding to the transitions of 4F9/2→4I15/2 and 4S3/2→4I15/2 of Er3+ ions.Under the excitation of 980 and 1550 nm lasers,the spectra of all of the samples exhibited similar peak positions but different intensities.When excited by the 980 nm laser,the intensity ratio of red to green emission increased with increasing Yb3+ doping concentration and decreased with increasing excitation power.In the case of 1550 nm excitation,the intensity ratio of red to green emission increased with increasing Yb3+ doping concentration and excitation power,thereby,improving the color purity of the red emission.The intensity of red emission was considerably stronger under 1550 nm excitation than that under 980 nm excitation.Therefore,the color of the proposed phosphors could be efficiently tuned by tailoring both the Yb3+ doping concentration and excitation power.
沈显良，邢明铭，田莹，付姚，彭勇，罗昔贤
Physics Department,Dalian Maritime University
摘 要：Er3+/Yb3+ co-doped SrY2O4 phosphors with high color purity and brightness were successfully synthesized via a solid-state reaction method.Luminescence spectrum studies showed that the main red peaks and the minor green peaks of upconversion emissions were located at approximately 634–681 nm and 543–570 nm,respectively,corresponding to the transitions of 4F9/2→4I15/2 and 4S3/2→4I15/2 of Er3+ ions.Under the excitation of 980 and 1550 nm lasers,the spectra of all of the samples exhibited similar peak positions but different intensities.When excited by the 980 nm laser,the intensity ratio of red to green emission increased with increasing Yb3+ doping concentration and decreased with increasing excitation power.In the case of 1550 nm excitation,the intensity ratio of red to green emission increased with increasing Yb3+ doping concentration and excitation power,thereby,improving the color purity of the red emission.The intensity of red emission was considerably stronger under 1550 nm excitation than that under 980 nm excitation.Therefore,the color of the proposed phosphors could be efficiently tuned by tailoring both the Yb3+ doping concentration and excitation power.
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