Fluidized roasting reduction kinetics of low-grade pyrolusite coupling with pretreatment of stone coal
来源期刊：International Journal of Minerals Metallurgy and Materials2013年第3期
论文作者：Ya-li Feng Zhen-lei Cai Hao-ran Li Zhu-wei Du Xin-wei Liu
文章页码：221 - 227
摘 要：Based on the fluidized roasting reduction technology of low-grade pyrolusite coupling with pretreatment of stone coal, the manganese reduction efficiency was investigated and technical conditions were optimized. It is found that the optimum manganese reduction efficiency can be up to 98.97% under the conditions that the mass ratio of stone coal to pyrolusite is 3:1, the roasting temperature of stone coal is 1000℃, the roasting temperature of pyrolusite is 800℃, and the roasting time is 2 h. Other low-grade pyrolusite ores in China from Guangxi, Hunan, and Guizhou Provinces were tested and all these minerals responded well, giving～99% manganese reduction efficiency. Meanwhile, the reduction kinetic model has been established. It is confirmed that the reduction process is controlled by the interface chemical reaction. The apparent activation energy is 36.397 kJ/mol.
Ya-li Feng1，Zhen-lei Cai1，Hao-ran Li2，Zhu-wei Du2，Xin-wei Liu1
1. School of Civil and Environmental Engineering, University of Science and Technology Beijing2. State Key Laboratory of Biochemical Engineering, Institute of Process Engineering, Chinese Academy of Sciences
摘 要：Based on the fluidized roasting reduction technology of low-grade pyrolusite coupling with pretreatment of stone coal, the manganese reduction efficiency was investigated and technical conditions were optimized. It is found that the optimum manganese reduction efficiency can be up to 98.97% under the conditions that the mass ratio of stone coal to pyrolusite is 3:1, the roasting temperature of stone coal is 1000℃, the roasting temperature of pyrolusite is 800℃, and the roasting time is 2 h. Other low-grade pyrolusite ores in China from Guangxi, Hunan, and Guizhou Provinces were tested and all these minerals responded well, giving～99% manganese reduction efficiency. Meanwhile, the reduction kinetic model has been established. It is confirmed that the reduction process is controlled by the interface chemical reaction. The apparent activation energy is 36.397 kJ/mol.
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