N,N－二异丁基二硫代氨基甲酸锑的合成及表征

来源期刊：中南大学学报(自然科学版)1996年第5期

论文作者：瞿龙 舒万艮 蒋汉瀛

文章页码：113 - 116

关键词：合成; 表征; 二异丁基二硫代氨基甲酸锑

Key words：synthesis; characterization; antimony dibutylisodithiocarbamate

摘    要：以二异丁胺、二硫化碳、三氧化二锑(或三硫化二锑)为原料合成了N,N－二异丁基二硫代氨基甲酸锑.考察了反应时间,反应温度、溶剂用量,重结晶溶剂等对合成工艺的影响,研究了该产品的提纯工艺,采用元素分析,红外光谱(IR),核磁共振技术(¹HNMR,¹³CNMR)探讨了其化学组成及分子结构,利用热分析技术(TG,DTA)研究了该化合物的热分解过程.

Abstract: Antimony N,N-dibutyl-isodithiocarbamate was synthesized. The influence of temperature, reacting time, the selection of solvent and its amount on the productivity of this synthsis method was investigated. Element analysis, IR, NMR and thermol analytical technique were used to study its chemical composition and thermol decomposition process.