Dissolution and repair of passive film on Cu-bearing 304L stainless steels immersed in H2SO4 solution
来源期刊：JOURNAL OF MATERIALS SCIENCE TECHNOLOG2018年第11期
论文作者：Xinrui Zhang Jinlong Zhao Tong Xi M.Babar Shahzad Chunguang Yang Ke Yang
文章页码：2149 - 2159
摘 要：The antibacterial Cu-bearing 304 L stainless steel is a new kind of structural and functional integrated metal material. In this work, evolution behavior of passive film of different heat treated Cu-bearing 304 L stainless steel immersed in 0.5 M H2SO4 solution was investigated by using electrochemical measurements, atomic force microscopy（AFM） observation and X-ray photoelectron spectroscopy（XPS） analysis.The results show that the solution and aging treated samples have the similar polarization behaviors. The passive film impedance experiences an initial decrease within 7 days followed by a subsequent increase,while the defect density of passive film presents the opposite trend. Meanwhile, the evolution of surface morphology and the estimated thickness of the passive film confirm that it experiences initial dissolution and follow-up repair. Furthermore, the Cr3+ content in passive film undergoes sequential reduction to increase, however the variation tendency of Cu2+ content is just opposite, indicating that the content variation of Cr and Cu in passive film reflects the competitive process of film dissolution and repair. In addition, compared with solution treated samples, aged samples have a bigger icorrvalue and the rougher passive film. This indicates that the passive film of solution treated steel is more compact and stable.
Xinrui Zhang1,2，Jinlong Zhao1,2，Tong Xi2，M.Babar Shahzad2，Chunguang Yang2，Ke Yang2
1. School of Materials Science and Engineering,University of Science and Technology of China2. Institute of Metal Research,Chinese Academy of Sciences
摘 要：The antibacterial Cu-bearing 304 L stainless steel is a new kind of structural and functional integrated metal material. In this work, evolution behavior of passive film of different heat treated Cu-bearing 304 L stainless steel immersed in 0.5 M H2SO4 solution was investigated by using electrochemical measurements, atomic force microscopy（AFM） observation and X-ray photoelectron spectroscopy（XPS） analysis.The results show that the solution and aging treated samples have the similar polarization behaviors. The passive film impedance experiences an initial decrease within 7 days followed by a subsequent increase,while the defect density of passive film presents the opposite trend. Meanwhile, the evolution of surface morphology and the estimated thickness of the passive film confirm that it experiences initial dissolution and follow-up repair. Furthermore, the Cr3+ content in passive film undergoes sequential reduction to increase, however the variation tendency of Cu2+ content is just opposite, indicating that the content variation of Cr and Cu in passive film reflects the competitive process of film dissolution and repair. In addition, compared with solution treated samples, aged samples have a bigger icorrvalue and the rougher passive film. This indicates that the passive film of solution treated steel is more compact and stable.
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