Microstructural characterization and mechanical properties of self-reinforced Si₃N₄ ceramics containing high oxynitride glass

Xuetao Luo, Lifu Chen, Qianjun Huang, Litong ZhangDepartment of Materials Science and Engineering, Xiamen University, Xiamen 361005, China College of Materials Science and Engineering, NPU, Xi’an 710072, China

摘 要：<正> Self-reinforced Si3N4 ceramics containing high oxynitride glass have been fabricated by the control of microstructure evolution and β-Si3N4 grain growth. The effects of the size distribution of the elongated β-Si3N4 grains, and the β-Si3N4 grain growth as well as the oxynitride glass chemical characteristic on the microstructure and mechanical properties were investigated. The experimental results show that the β-Si3N4 grains in high oxynitride glass grow to elongated rod-like crystals and form the stereo-network structure. Under the sintering conditions of 1800℃ and 60 min, a quite uniform microstructure with an average aspect ratio of 6.5 and an average of 1μm can be obtained. A large amount of oxynitride glass phase with high nitrogen content enhances the elevated temperature fracture toughness because of its high softening temperature and high viscosity. In the present material, the crack deflection and pullout of the elongated rod-like β-Si3N4 grains are the primary toughening mechanisms.

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