Luminescence of Er3+ Doped Titanium Barium Glass Microsphere under 514 nm Excitation
来源期刊:JOURNAL OF RARE EARTHS2006年增刊第2期
论文作者:Liu Ling Yuan Fang Wang Jiyou Wang Lipu Wang Min
Key words:luminescence; optical microacvity; glass microsphere; whispering galley modes; rare earths;
Abstract: The titanium barium glass microspheres doped with Er2O3 were designed and prepared. The components of the glass sample were 25TiO2-27BaCO3-8Ba(NO3)2-5ZnO2-10CaCO3-5H3BO3-10SiO2-7water glass-3Er2O3 (%, mass fraction). The emission spectra of titanium barium glass matrix and the titanium barium glass microsphere under 514 nm excitation were measured with micro-Raman spectrometer. Whispering gallery modes in the emission spectra from a 31 μm glass microsphere were observed. Many regularly spaced, sharp peaks appeared in the emission spectra of the Er2O3-doped glass microsphere. The wavelength separation between the two adjacent peaks is 1.92 nm for the 31 μm microsphere. According to the Lorenz-Mie formula, the calculated value of the wavelength separation between the two adjacent peaks is 1.95 nm. The observed resonances could be assigned by using the well-known Lorenz-Mie formula.
Liu Ling1,Yuan Fang1,Wang Jiyou1,Wang Lipu2,Wang Min1
(1.College of Applied Sciences, Beijing University of Technology, Beijing 100022, China;
2.Department of Facial Features and Medical Treatment Technique, Xingtai Medical College, Xingtai 054056, China)
Abstract:The titanium barium glass microspheres doped with Er2O3 were designed and prepared. The components of the glass sample were 25TiO2-27BaCO3-8Ba(NO3)2-5ZnO2-10CaCO3-5H3BO3-10SiO2-7water glass-3Er2O3 (%, mass fraction). The emission spectra of titanium barium glass matrix and the titanium barium glass microsphere under 514 nm excitation were measured with micro-Raman spectrometer. Whispering gallery modes in the emission spectra from a 31 μm glass microsphere were observed. Many regularly spaced, sharp peaks appeared in the emission spectra of the Er2O3-doped glass microsphere. The wavelength separation between the two adjacent peaks is 1.92 nm for the 31 μm microsphere. According to the Lorenz-Mie formula, the calculated value of the wavelength separation between the two adjacent peaks is 1.95 nm. The observed resonances could be assigned by using the well-known Lorenz-Mie formula.
Key words:luminescence; optical microacvity; glass microsphere; whispering galley modes; rare earths;
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