Electronic structure and optical properties of plutonium dioxide from first-principles calculations
来源期刊：Rare Metals2016年第8期
论文作者：Jun Chen Da-qiao Meng Qiu-Yun Chen Wen-Hua Luo
文章页码：643 - 648
摘 要：The electronic structure and optical properties of plutonium dioxide were calculated using the generalized gradient approximation with a Hubbard parameter U（GGA+U） for considering the strong coulomb correlation between localized Pu 5f electrons based on the first-principles density functional theory. The calculated results show that PuO2 is a semiconductor material with the band gap of 1.8 eV, which is in good agreement with the corresponding experimental data. Furthermore, the dielectric function, reflectivity, refractive index, and extinction coefficient were calculated and analyzed using the Kramers–Kronig relationship for PuO2. The calculated results were compared with the experimental data from the published literature.
Jun Chen，Da-qiao Meng，Qiu-Yun Chen，Wen-Hua Luo
Science and Technology on Surface Physics and Chemistry Laboratory
摘 要：The electronic structure and optical properties of plutonium dioxide were calculated using the generalized gradient approximation with a Hubbard parameter U（GGA+U） for considering the strong coulomb correlation between localized Pu 5f electrons based on the first-principles density functional theory. The calculated results show that PuO2 is a semiconductor material with the band gap of 1.8 eV, which is in good agreement with the corresponding experimental data. Furthermore, the dielectric function, reflectivity, refractive index, and extinction coefficient were calculated and analyzed using the Kramers–Kronig relationship for PuO2. The calculated results were compared with the experimental data from the published literature.
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