Ceria supported nickel catalysts for CO removal from H2-rich gas
来源期刊：JOURNAL OF RARE EARTHS2016年第12期
论文作者：高志明 代倩子 马宏伟 李展平
文章页码：1213 - 1220
摘 要：CO in H2-rich gas must be removed to meet various requirements in industrial applications. Four methods, i.e., the precipitation method using aqueous ammonia, the complexing method using urea, the complexing method using citric acid and the precipitation method using ammonium carbonate, were adopted to prepare samples NiO/CeO2 as catalyst precursors for removal of CO from H2-rich gas via selective methanation reaction. The sample NiO/CeO2 prepared by the precipitation method using aqueous ammonia as precipitant exhibited the highest catalytic activity both for CO methanation and for CO2 methanation after reduction prior to the catalytic reaction. Chlorine ion was then doped to suppress CO2 conversion. Effect of chlorine doping was investigated. Over the optimal catalyst 40%Ni(Cl0.2)/CeO2, CO in the H2-rich gas was removed to below 10 ppm with selectivity of 60% or higher at reaction temperatures 230–250 ℃ in the test period of 75 h.
高志明1，代倩子1，马宏伟1，李展平2
1. School of Chemistry, Beijing Institute of Technology2. Analysis Center, Tsinghua University
摘 要：CO in H2-rich gas must be removed to meet various requirements in industrial applications. Four methods, i.e., the precipitation method using aqueous ammonia, the complexing method using urea, the complexing method using citric acid and the precipitation method using ammonium carbonate, were adopted to prepare samples NiO/CeO2 as catalyst precursors for removal of CO from H2-rich gas via selective methanation reaction. The sample NiO/CeO2 prepared by the precipitation method using aqueous ammonia as precipitant exhibited the highest catalytic activity both for CO methanation and for CO2 methanation after reduction prior to the catalytic reaction. Chlorine ion was then doped to suppress CO2 conversion. Effect of chlorine doping was investigated. Over the optimal catalyst 40%Ni(Cl0.2)/CeO2, CO in the H2-rich gas was removed to below 10 ppm with selectivity of 60% or higher at reaction temperatures 230–250 ℃ in the test period of 75 h.
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