Extractant(2,3-dimethylbutyl)(2,4,40-trimethylpentyl) phosphinic acid(INET-3) impregnated onto XAD-16 and its extraction and separation performance for heavy rare earths from chloride media
来源期刊:JOURNAL OF RARE EARTHS2017年第12期
论文作者:Junlian Wang Meiying Xie Juanjuan Ma Huajun Wang Shengming Xu
文章页码:1239 - 1247
摘 要:(2,3-Dimethylbutyl)(2,4,40-trimethylpentyl)phosphinic acid(INET-3) was impregnated onto dry macroporous resins XAD-16 and pretreated XAD-16 with ethyl alcohol and HCl(Pre-XAD-16) to prepare the solvent impregnated resins SIRs-INET-3/XAD-16 and SIRs-INET-3/Pre-XAD-16. The molecular weight distribution of the low molecular weight(LMW) polymers washed off by ethyl alcohol during XAD-16 pretreatment was determined by gel permeation chromatography(GPC). The macroporous resins(XAD-16 & Pre-XAD-16), the corresponding solvent impregnated resins(SIRs-INET-3/XAD-16 &SIRs-INET-3/Pre-XAD-16) and the PVA coated SIRs-INET-3/Pre-XAD-16 with boric acid as cross-linking agent were characterized by FT-IR, SEM-EDS and TGA. The effects of XAD-16 pretreatment and PVA coating technology on RE(III) adsorption equilibrium time, INET-3 losses during extraction and adsorption capacity were investigated. The adsorption kinetics, selectivity and stripping behaviors of SIRs-INET-3/XAD-16 were further studied. The washed off LMW polymers had the Mn of 36,656, Mw of 40,310 and polydispersity coefficient of 1.10. The SIRs-INET-3/XAD-16 had shorter equilibrium time,less INET-3 loss and more Tm(III) adsorption capacity than the SIRs-INET-3/Pre-XAD-16. The PVA coated SIRs-INET-3/Pre-XAD-16 had less INET-3 loss and more Tm(III) adsorption capacity but longer equilibrium time than the uncoated SIRs-INET-3/Pre-XAD-16. The adsorption of RE(III) on the SIRsINET-3/XAD-16 followed the pseudo-second-order kinetic model. The Tm(III) accumulative adsorption amounts onto SIRs-INET-3/XAD-16 after eight extraction stages was 23.6 mg/g. The separation factors of adjacent heavy RE(III) βEr/Ho, βTm/Er, βYb/Tm and βLu/Yb values were 1.76, 2.59, 2.56 and 1.19,respectively. The adsorbed Lu(III) onto the SIRs-INET-3/XAD-16 can be stripped completely by 1.0 mol/L H2SO4.
Junlian Wang1,Meiying Xie1,Juanjuan Ma1,Huajun Wang1,Shengming Xu2
1. Civil and Resource Engineering School, University of Science and Technology Beijing2. Institute of Nuclear and New Energy Technology, Tsinghua University
摘 要:(2,3-Dimethylbutyl)(2,4,40-trimethylpentyl)phosphinic acid(INET-3) was impregnated onto dry macroporous resins XAD-16 and pretreated XAD-16 with ethyl alcohol and HCl(Pre-XAD-16) to prepare the solvent impregnated resins SIRs-INET-3/XAD-16 and SIRs-INET-3/Pre-XAD-16. The molecular weight distribution of the low molecular weight(LMW) polymers washed off by ethyl alcohol during XAD-16 pretreatment was determined by gel permeation chromatography(GPC). The macroporous resins(XAD-16 & Pre-XAD-16), the corresponding solvent impregnated resins(SIRs-INET-3/XAD-16 &SIRs-INET-3/Pre-XAD-16) and the PVA coated SIRs-INET-3/Pre-XAD-16 with boric acid as cross-linking agent were characterized by FT-IR, SEM-EDS and TGA. The effects of XAD-16 pretreatment and PVA coating technology on RE(III) adsorption equilibrium time, INET-3 losses during extraction and adsorption capacity were investigated. The adsorption kinetics, selectivity and stripping behaviors of SIRs-INET-3/XAD-16 were further studied. The washed off LMW polymers had the Mn of 36,656, Mw of 40,310 and polydispersity coefficient of 1.10. The SIRs-INET-3/XAD-16 had shorter equilibrium time,less INET-3 loss and more Tm(III) adsorption capacity than the SIRs-INET-3/Pre-XAD-16. The PVA coated SIRs-INET-3/Pre-XAD-16 had less INET-3 loss and more Tm(III) adsorption capacity but longer equilibrium time than the uncoated SIRs-INET-3/Pre-XAD-16. The adsorption of RE(III) on the SIRsINET-3/XAD-16 followed the pseudo-second-order kinetic model. The Tm(III) accumulative adsorption amounts onto SIRs-INET-3/XAD-16 after eight extraction stages was 23.6 mg/g. The separation factors of adjacent heavy RE(III) βEr/Ho, βTm/Er, βYb/Tm and βLu/Yb values were 1.76, 2.59, 2.56 and 1.19,respectively. The adsorbed Lu(III) onto the SIRs-INET-3/XAD-16 can be stripped completely by 1.0 mol/L H2SO4.
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