C₆₀硝基化合物的合成与性质

来源期刊：中南大学学报(自然科学版)1996年第1期

论文作者：黄克雄 孙红英 李晶 李新海 黄欢 孙铭良

文章页码：109 - 112

关键词：C₆₀, nitro-derivatives; synthesis; property

Key words：C₆₀, nitro-derivatives; synthesis; property

摘    要：在惰性介质CCl₄溶剂中,将C₆₀ 分别与浓HNO₃及NO₂反应制备C₆₀硝基化合物,并通过红外光谱、紫外光谱、元素分析等方法确定了C₆₀硝基化合物的结构为 C₆₀(NO₂)x(OH)y·其中,C₆₀与HNO₃反应合成时,x为2～3,y为12～14;与NO₂反应合成时,x为3～5,y为12～16。

Abstract: C₆₀ nitro-derivatives were prepared by reacting C₆₀ in the inert CCl₄ solution with concentrated HNO₃ and NO₂ gas respectively. The products were studied by means of IR, UV and elemental analysis etc. And the formulas were ascertained to be C₆₀(NO₂)x(OH)y where x=2～3,y= 12～14 or x= 3～5,y= 12～16 in the product obtained by concentrated HNO₃ or NO₂ gas respectively.