White light emission of Eu3+/Ag co-doped Y2Si2O7
来源期刊:Journal of Rare Earths2014年第9期
论文作者:邓宇航 宋文申 董伟乐 代如成 王中平 张增明 丁泽军
文章页码:779 - 786
摘 要:The Eu3+/Ag co-doped rare earth disilicate Y2Si2O7 microcrystal was synthesized by sol-gel method. Through controlling the thermal treatment process of Y2Si2O7:Eu3+/Ag precursor, various phases(amorphous, α, β, γ, δ) were prepared. White light emission was observed under UV light excitation in the samples heavily doped with Ag. The white light was realized by combining the intense red emission of Eu3+, the green emission attributed to the very small molecule-like, non-plasmonic Ag particles(ML-Ag-particles), and the blue emission due to Ag ions. Results demonstrated that Eu3+/Ag co-doped Y2Si2O7 microcrystal could be potentially applied as white light emission phosphors for UV LED chips.
邓宇航1,宋文申2,董伟乐2,代如成3,王中平3,张增明3,丁泽军1,2
1. Hefei National Laboratory for Physical Sciences at Microscale2. Department of Physics University of Science and Technology of China3. The Center of Physical Experiments University of Science and Technology of China
摘 要:The Eu3+/Ag co-doped rare earth disilicate Y2Si2O7 microcrystal was synthesized by sol-gel method. Through controlling the thermal treatment process of Y2Si2O7:Eu3+/Ag precursor, various phases(amorphous, α, β, γ, δ) were prepared. White light emission was observed under UV light excitation in the samples heavily doped with Ag. The white light was realized by combining the intense red emission of Eu3+, the green emission attributed to the very small molecule-like, non-plasmonic Ag particles(ML-Ag-particles), and the blue emission due to Ag ions. Results demonstrated that Eu3+/Ag co-doped Y2Si2O7 microcrystal could be potentially applied as white light emission phosphors for UV LED chips.
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