Particular properties of Ti2O and TiNx nanoparticles prepared by thermal decomposition
来源期刊:Rare Metals2008年第6期
论文作者:LI Xiongping, WU Jieda, WEN Ming, TANG Xiao, and LIU Yongqiang Department of Chemistry, Tongji University, Shanghai , China
文章页码:598 - 602
摘 要:Particular properties of Ti2O and TiNx prepared by thermal decomposition were introduced. A precursor prepared by titanium powder react- ing with oxalate acid was thermally decomposed in nitrogen atmosphere at 840°C for 15 min, and relatively pure Ti2O was then obtained. Conductive TiNx was also prepared after altering reaction conditions. Samples were characterized by resistivity, X-ray powder diffraction, transmission electron microscope, Ultraviolet-Visible diffuse reflection, and electromagnetic shielding efficiency. The results indicate that both Ti2O and TiNx have good conductivity. Moreover, Ti2O shows a better solar photocatalytic activity and TiNx does well in the electro- magnetic shield.
LI Xiongping, WU Jieda, WEN Ming, TANG Xiao, and LIU Yongqiang Department of Chemistry, Tongji University, Shanghai 200092, China
摘 要:Particular properties of Ti2O and TiNx prepared by thermal decomposition were introduced. A precursor prepared by titanium powder react- ing with oxalate acid was thermally decomposed in nitrogen atmosphere at 840°C for 15 min, and relatively pure Ti2O was then obtained. Conductive TiNx was also prepared after altering reaction conditions. Samples were characterized by resistivity, X-ray powder diffraction, transmission electron microscope, Ultraviolet-Visible diffuse reflection, and electromagnetic shielding efficiency. The results indicate that both Ti2O and TiNx have good conductivity. Moreover, Ti2O shows a better solar photocatalytic activity and TiNx does well in the electro- magnetic shield.
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