Glycidyl methacrylate-compatibilized poly(lactic acid)/hemp hurd biocomposites: Processing, crystallization, and thermo-mechanical response
来源期刊:JOURNAL OF MATERIALS SCIENCE TECHNOLOG2018年第2期
论文作者:Belas Ahmed Khan Venkata Chevali Hao Wang
文章页码:387 - 397
摘 要:Poly(lactic acid)-based biocomposites were developed with hemp hurd(Cannabis sativa L.) with grafting-based interfacial compatibilization. Poly(lactic acid) was extruded with hemp hurd and glycidyl methacrylate as the polymer/hurd interfacial compatibilizer, and injection molded. Interfacial compatibility between poly(lactic acid) and hemp hurd increased with grafted glycidyl methacrylate in comparison to the non-compatibilized control, as corroborated by scanning electron microscopy fractography and mechanical analysis, which showed increases in the glycidyl methacrylate-grafted 20%(w/w)hemp hurd/poly(lactic acid) biocomposite, retaining 94% of the neat polymer strength, with increases in crystallinity, and showing a range of thermo-mechanical properties desirable for rigid biocomposite applications.
Belas Ahmed Khan1,Venkata Chevali1,Hao Wang1
1. Centre for Future Materials, University of Southern Queensland
摘 要:Poly(lactic acid)-based biocomposites were developed with hemp hurd(Cannabis sativa L.) with grafting-based interfacial compatibilization. Poly(lactic acid) was extruded with hemp hurd and glycidyl methacrylate as the polymer/hurd interfacial compatibilizer, and injection molded. Interfacial compatibility between poly(lactic acid) and hemp hurd increased with grafted glycidyl methacrylate in comparison to the non-compatibilized control, as corroborated by scanning electron microscopy fractography and mechanical analysis, which showed increases in the glycidyl methacrylate-grafted 20%(w/w)hemp hurd/poly(lactic acid) biocomposite, retaining 94% of the neat polymer strength, with increases in crystallinity, and showing a range of thermo-mechanical properties desirable for rigid biocomposite applications.
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