简介概要

Preparation and upconversion luminescence of monodisperse Y2O2S:Yb/ Ho-silica/aminosilane core-shell nanoparticles

来源期刊:Journal of Rare Earths2010年第4期

论文作者:庞涛 曹望和 邢明铭 冯威 徐书婧 罗昔贤

文章页码:509 - 512

摘    要:Y2O2S:Yb/Ho-silica/aminosilane core-shell nanoparticles were prepared by a solid-gas method in combination with polyvinylpyr-rolidone assisted one-step ammoniating method. The core was a single Y2O2S:Yb/Ho with 80 nm in diameter and the shell was silica/aminosilane with around 5 nm in thickness. The results of sedimentation experiment indicated that the nanoparticles could be well-dispersed in ethanol and water to form stable colloids. Since the coating weakened lattice vibration energies of the Y2O2S:Yb/Ho particles, the proportion of upconversion processes in the depletion of Ho3+ 5I6 level were increased, resulting in increase of green light and decrease of red light.

详情信息展示

Preparation and upconversion luminescence of monodisperse Y2O2S:Yb/ Ho-silica/aminosilane core-shell nanoparticles

庞涛,曹望和,邢明铭,冯威,徐书婧,罗昔贤

Optoelectronic Technology Institute, Dalian Maritime University

摘 要:Y2O2S:Yb/Ho-silica/aminosilane core-shell nanoparticles were prepared by a solid-gas method in combination with polyvinylpyr-rolidone assisted one-step ammoniating method. The core was a single Y2O2S:Yb/Ho with 80 nm in diameter and the shell was silica/aminosilane with around 5 nm in thickness. The results of sedimentation experiment indicated that the nanoparticles could be well-dispersed in ethanol and water to form stable colloids. Since the coating weakened lattice vibration energies of the Y2O2S:Yb/Ho particles, the proportion of upconversion processes in the depletion of Ho3+ 5I6 level were increased, resulting in increase of green light and decrease of red light.

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