Microstructural evolution and characteristics during sintering of submicron Ti(C,N)-based cermet
来源期刊:中国有色金属学报(英文版)2003年第6期
论文作者:郑勇 熊惟皓 游敏 刘文俊
文章页码:1424 - 1429
Key words:submicron Ti(C,N)-based cermet; microstructure; evolution; forming mechanism
Abstract: Ti(C,N)-based cermets were prepared with submicron powders. The microstructure evolution and characteristics during the sintering of cermet were studied by TEM, SEM, EDX and XRD. The forming mechanism of the structures was also studied. There exist inner rim and outer rim between the hard cores and the binder. The inner rim is enriched in Mo and W compared with the outer rim, and is formed during the solid sintering by counter diffusion of TiC, Mo2C and WC. The outer rim is formed during the liquid sintering by Ostwald ripening mechanism.