Ni/Carbon Hybrid Prepared by Hydrothermal Carbonization and Thermal Treatment as Support for PtRu Nanoparticles for Direct Methanol Fuel Cell
来源期刊：JOURNAL OF MATERIALS SCIENCE TECHNOLOG2013年第8期
论文作者：Marcelo Marques Tusi Michele Brandalise Nataly Soares de Oliveira Polanco Olandir Vercino Correa Antonio Carlos da Silva Juan Carlo Villalba Fauze Jaco Anaissi Almir Oliveira Neto Estevam Vitorio Spinac
文章页码：747 - 751
摘 要：<正>Ni/Carbon was prepared in two steps:initially cellulose as carbon source and NiCI2·6H20 as catalyst of the carbonization process were submitted to hydrothermal treatment at 200℃and further to thermal treatment at 900℃under argon atmosphere.The obtained material contains Ni nanoparticles with face-centered cubic （fcc） structure dispersed on amorphous carbon with graphitic domains.PtRu/C electrocatalysts（carbon-supported PtRu nanoparticles） were prepared by an alcohol-reduction process using Ni/Carbon as support.The materials were characterized by thermogravimetric analysis,energy-dispersive X-ray spectroscopy,Fourier transform infrared spectroscopy.X-ray diffraction,transmission electron microscopy and tested as anodes in single direct methanol fuel cell（DMFC）.The performances of PtRu/C electrocatalysts using Ni/Carbon as support were superior to those obtained for FtRu/C using commercial carbon black Vulcan XC72 as support.
Marcelo Marques Tusi1，Michele Brandalise2，Nataly Soares de Oliveira Polanco2，Olandir Vercino Correa2，Antonio Carlos da Silva2，Juan Carlo Villalba3，Fauze Jaco Anaissi3，Almir Oliveira Neto2，Estevam Vitorio Spinac2
摘 要：<正>Ni/Carbon was prepared in two steps:initially cellulose as carbon source and NiCI2·6H20 as catalyst of the carbonization process were submitted to hydrothermal treatment at 200℃and further to thermal treatment at 900℃under argon atmosphere.The obtained material contains Ni nanoparticles with face-centered cubic （fcc） structure dispersed on amorphous carbon with graphitic domains.PtRu/C electrocatalysts（carbon-supported PtRu nanoparticles） were prepared by an alcohol-reduction process using Ni/Carbon as support.The materials were characterized by thermogravimetric analysis,energy-dispersive X-ray spectroscopy,Fourier transform infrared spectroscopy.X-ray diffraction,transmission electron microscopy and tested as anodes in single direct methanol fuel cell（DMFC）.The performances of PtRu/C electrocatalysts using Ni/Carbon as support were superior to those obtained for FtRu/C using commercial carbon black Vulcan XC72 as support.
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