季铵盐 A-l 的相转移催化性能
来源期刊：中南大学学报(自然科学版)1998年第4期
论文作者：成本诚 于澍 谢文林
文章页码：95 - 98
关键词：催化剂;季铵盐;有机合成;相转移催化
Key words：catalyst; quaternary ammonium salt; organic synthesis; phase transfer catalysis
摘 要：经实验研究发现具有结构为(C8～10 H17～21 )3N +CH3Cl -的季铵盐A－l是一种优良的相转移催化剂．在酯化、氧化和烷基化反应中其催化活性要优于聚乙二醇、季磷盐和其它短碳链的季铵盐．A－l在分离过程中不乳化，因而使合成产品易于分离提纯．该催化剂可循环使用，循环使用次数与温度有关．
Abstract: This paper describes that quaternary ammonium salt, A l((C8～10 H17～21 )3N +CH3Cl-), is employed as a kind of fine phase transfer catalyst. The activity of A l in esterfication, oxidation and alkylation, is better than that of polyethylene glycol, quaternary phosphonium salt, and other short chain alkyl quaternary ammonium salts. A l is unemulsifiable, so it can be separated easily and recycled. The recycling times of circulation are related to temperature.
