Electrochemical performance of a nickel-rich LiNi0.6Co0.2Mn0.2O2 cathode material for lithium-ion batteries under different cut-off voltages
来源期刊：International Journal of Minerals Metallurgy and Materials2017年第3期
论文作者：Kai-lin Cheng Dao-bin Mu Bo-rong Wu Lei Wang Ying Jiang Rui Wang
文章页码：342 - 351
摘 要：A spherical-like Ni0.6Co0.2Mn0.2（OH）2 precursor was tuned homogeneously to synthesize LiNi0.6Co0.2Mn0.2O2 as a cathode material for lithium-ion batteries.The effects of calcination temperature on the crystal structure,morphology,and the electrochemical performance of the as-prepared LiNi0.6Co0.2Mn0.2O2 were investigated in detail.The as-prepared material was characterized by X-ray diffraction,scanning electron microscopy,laser particle size analysis,charge–discharge tests,and cyclic voltammetry measurements.The results show that the spherical-like LiNi0.6Co0.2Mn0.2O2 material obtained by calcination at 900°C displayed the most significant layered structure among samples calcined at various temperatures,with a particle size of approximately 10 μm.It delivered an initial discharge capacity of 189.2 m Ah×g-1 at 0.2C with a capacity retention of 94.0% after 100 cycles between 2.7 and 4.3 V.The as-prepared cathode material also exhibited good rate performance,with a discharge capacity of 119.6 m Ah×g-1 at 5C.Furthermore,within the cut-off voltage ranges from 2.7 to 4.3,4.4,and 4.5 V,the initial discharge capacities of the calcined samples were 170.7,180.9,and 192.8 m Ah×g-1,respectively,at a rate of 1C.The corresponding retentions were 86.8%,80.3%,and 74.4% after 200 cycles,respectively.
Kai-lin Cheng1，Dao-bin Mu1，Bo-rong Wu1,2，Lei Wang1，Ying Jiang1，Rui Wang1
1. Beijing Key Laboratory of Environmental Science and Engineering,School of Materials Science and Engineering,Beijing Institute of Technology
摘 要：A spherical-like Ni0.6Co0.2Mn0.2（OH）2 precursor was tuned homogeneously to synthesize LiNi0.6Co0.2Mn0.2O2 as a cathode material for lithium-ion batteries.The effects of calcination temperature on the crystal structure,morphology,and the electrochemical performance of the as-prepared LiNi0.6Co0.2Mn0.2O2 were investigated in detail.The as-prepared material was characterized by X-ray diffraction,scanning electron microscopy,laser particle size analysis,charge–discharge tests,and cyclic voltammetry measurements.The results show that the spherical-like LiNi0.6Co0.2Mn0.2O2 material obtained by calcination at 900°C displayed the most significant layered structure among samples calcined at various temperatures,with a particle size of approximately 10 μm.It delivered an initial discharge capacity of 189.2 m Ah×g-1 at 0.2C with a capacity retention of 94.0% after 100 cycles between 2.7 and 4.3 V.The as-prepared cathode material also exhibited good rate performance,with a discharge capacity of 119.6 m Ah×g-1 at 5C.Furthermore,within the cut-off voltage ranges from 2.7 to 4.3,4.4,and 4.5 V,the initial discharge capacities of the calcined samples were 170.7,180.9,and 192.8 m Ah×g-1,respectively,at a rate of 1C.The corresponding retentions were 86.8%,80.3%,and 74.4% after 200 cycles,respectively.
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