Influences of phase composition on Sr3SiO5:Eu2+ luminous performance
来源期刊：JOURNAL OF RARE EARTHS2013年第5期
论文作者：王晓春 张希艳 王辰 秦伟达 孙佳逊
文章页码：456 - 460
摘 要：α’-Sr2SiO4 :Eu2+ phase always coexists with the Sr3SiO5:Eu2+ phase when it is synthesized by a high-temperature solid-state method. This may affect the luminescent properties of the Sr3SiO5:Eu2+ phosphors. We investigated the decomposition reaction of Sr3SiO5 during the cooling process with the quenching method. The results indicated that Sr3SiO5 was a stable compound above 1250 ℃. The Sr3SiO5 phase decomposed into α’-Sr2SiO4 and SrO below 1250℃. The α’-Sr2SiO4 :Eu2+ phase would coexist with the Sr3SiO5:Eu2+ phase because of the decomposition reaction of Sr3SiO5 , making the luminescent wavelength of coexistence sample move to the short-wavelength compared with the luminescent wavelength of Sr3SiO5:Eu2+. Pure phase Sr3SiO5:Eu2+ could be obtained by the rapid cooling method to suppress Sr3SiO5 decomposition. When the cooling rate was 20℃/min, nearly pure phase Sr3SiO5:Eu2+ could be produced.
王晓春，张希艳，王辰，秦伟达，孙佳逊
Engineering Research Center of Optoelectronic Functional Materials of the Ministry of Education,Changchun University of Science and Technology
摘 要：α’-Sr2SiO4 :Eu2+ phase always coexists with the Sr3SiO5:Eu2+ phase when it is synthesized by a high-temperature solid-state method. This may affect the luminescent properties of the Sr3SiO5:Eu2+ phosphors. We investigated the decomposition reaction of Sr3SiO5 during the cooling process with the quenching method. The results indicated that Sr3SiO5 was a stable compound above 1250 ℃. The Sr3SiO5 phase decomposed into α’-Sr2SiO4 and SrO below 1250℃. The α’-Sr2SiO4 :Eu2+ phase would coexist with the Sr3SiO5:Eu2+ phase because of the decomposition reaction of Sr3SiO5 , making the luminescent wavelength of coexistence sample move to the short-wavelength compared with the luminescent wavelength of Sr3SiO5:Eu2+. Pure phase Sr3SiO5:Eu2+ could be obtained by the rapid cooling method to suppress Sr3SiO5 decomposition. When the cooling rate was 20℃/min, nearly pure phase Sr3SiO5:Eu2+ could be produced.
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