简介概要

Exchange interactions and magnetic properties of intermetallic compounds

来源期刊:中国有色金属学报(英文版)2003年第1期

论文作者:郭光华

文章页码:1 - 5

Key words:intermetallic compound; magnetic phase transition; exchange interaction

Abstract: The temperature dependence of lattice parameters a and c of intermetallic compounds RMn2Ge2(R=La, Sm and Gd)were measured in the temperature range of 10-800K by using the X-ray diffractometer. It is found that the high temperature magnetic transitions of Mn-subsystem in light rare earth compounds from paramagnetic to antiferromagnetic state accompany the negative magnetoelastic anomalies of lattice parameters c, where a does not change. This indicates that the antiferromagnetic component of intralayer Mn-Mn exchange coupling is correlated with lattice constant c. The low temperature first order ferromagnetism→antiferromagnetism transitions(or antiferromagnetism→ferromagnetism transition) of Mn-subsystem in SmMn2Ge2 and GdMn2Ge2 accompany the abruptly decrease(or increase) of lattice parameter a, and Δa/a≈0.15%. This demonstrates that the interlayer Mn-Mn exchange interaction is very sensitive to the intralayer Mn-Mn distance. The critical value of lattice constant ak, at which the interlayer Mn-Mn coupling changes its sign, is 4.0445×10-10 m. Based on the molecular field model of exchange interaction the magnetic curves of GdMn2Ge2 single crystal at different temperatures were calculated and a good agreement with experimental data had gotten. The Gd-Gd, Gd-Mn, intralayer Mn-Mn and interlayer Mn-Mn exchange coupling parameters were estimated.

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