Electrochemical Reduction of Yttrium Ions
来源期刊:Journal of Rare Earths1992年第3期
论文作者:段淑贞 赵立忠 魏寿昆
文章页码:183 - 188
摘 要:<正> The cathodic electrode process of Y3+ ions on the Mo electrode in the LiCl-KCl molten salt withYCl3(3wt%) in the temperature range of 450~530℃ has been investigated using cyclic voltammetry andchronopotentiometry.The convolution technique has been applied to the treatment of cyclic voltammogram.Theresults show that the reduction mechanism of Y3+ ion is Y3++3e=Y,a simple one-step process.The cathodicprocess is very close to a reversible process under lower scanning rates,and is diffusion-controlled.The cathodicproduct is an insoluble product.
段淑贞,赵立忠,魏寿昆
摘 要:<正> The cathodic electrode process of Y3+ ions on the Mo electrode in the LiCl-KCl molten salt withYCl3(3wt%) in the temperature range of 450~530℃ has been investigated using cyclic voltammetry andchronopotentiometry.The convolution technique has been applied to the treatment of cyclic voltammogram.Theresults show that the reduction mechanism of Y3+ ion is Y3++3e=Y,a simple one-step process.The cathodicprocess is very close to a reversible process under lower scanning rates,and is diffusion-controlled.The cathodicproduct is an insoluble product.
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