图书来源:二元合金相图及中间相晶体结构 二元合金相图及中间相晶体结构
作 者:唐仁政 田荣璋
出版时间:2009-05
定 价:320元
图书ISBN:978-7-81105-831-4
出版单位:中南大学出版社
Jingchao Chen1), Jing Feng1), B. Xiao2), K.H. Zhang1), Y.P. Du1), Z.J. Hong1) and R. Zhou1) 1) Key Laboratory of Advanced Materials of Precious-Nonferrous Metals, Education Ministry of China, and Key Lab of Advanced Materials of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, China 2) State Key Laboratory of Mechanical Behavior of Materials, School of Materials Science and Engineering, Xi an Jiaotong University, Xi an 710049, China
摘 要:The electric contact material of Ag/SnO2 composite was achieved by reactive synthesis method. The compositions and microstructure of Ag/SnO2 composite were analyzed and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and high-resolution electron microscopy (HRTEM). The structural feature was typical of the particle reinforced composites. The HRTEM images revealed that the observed Ag/SnO2 interface was absence of the precipitated phase and the lattice contrast across the interface was clear and sharp. The average particle size of SnO2 in composite was near 50 nm and it was well dispersed in spherical shape. The thermodynamic mechanism of reactive synthesis method was also discussed. The electronic density distribution analysis of the interface showed the charges of Ag atoms transmitted to O atoms and the conductivity of the material was also affected. No extra compounds expected such as AgxOy formed at interface. The distribution of electrons was of inequality near the interface which explained why the mechanical property of the metal/ceramic materials was improved but the machining property declined.
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