Effect of diffusion on coating microstructure and oxidation resistance of aluminizing steel
来源期刊:中国有色金属学报(英文版)2001年第6期
论文作者:夏原 于升学 姚枚 李铁藩
文章页码:817 - 821
Key words:hot-dip aluminium; dip diffusion aluminum; oxidation resistance at hightemperature; surface coating; microstructure
Abstract: The effect of diffuse treatment on coating microstructure and oxidation resistance at high-temperature of hot-dip aluminum were studied by means of TEM, SEM and XRD. The results show that, the diffusion temperature has significant effect on structure of coatings and its oxidation resistance. After diffusion at 750℃, the coating consists of thick outer surface layer (Fe2Al5+FeAl2), thin internal layer (FeAl+stripe FeAl2), and its oxidation resistance is poor. After diffusion at 950℃, the outer surface layer is composed of single FeAl2 phase, the internal layer is composed of FeAl phase, and its oxidation resistance declines due to the occurrence of early stage internal oxidation cracks in the coating. After diffusion at 850℃, the outer surface layer becomes thinner and consists of FeAl2+Fe2Al5 (small amount), the internal layer becomes thicker and consists of FeAl+spherical FeAl2,and the spheroidized FeAl2 phase in the internal layer and its existing in FeAl phase steadily improve the oxidation resistance of the coating.