One-dimensional (1D) europium coordination polymer wires:Synthesis,characterization and photoluminescence properties
来源期刊:Journal of Rare Earths2010年第S1期
论文作者:罗龙飞 徐蓉 赵东 钟声亮
文章页码:106 - 110
摘 要:1D europium coordination polymer wires were successfully prepared by reacting europium chloride with tributyl phosphate(TBP) at 160 oC for 12 h. The products were characterized by XRD,IR,TG,DTA,SEM,and EDS. SEM results showed that the wires were with diameters ranging from several hundreds of nanometers to ~5 μm and lengths going up to several hundreds of micrometers. Influencing factors such as the dosage of reactants and reaction time on the preparation were systematically investigated. Strong emission centering at 590 nm was realized in the coordination polymer wires on excitation at 395 nm.
罗龙飞1,徐蓉1,赵东1,钟声亮1,2
1. College of Chemistry and Chemical Engineering,Jiangxi Normal University2. Division of Nanomaterials and Chemistry,Hefei National Laboratory for Physical Sciences at Microscale,University of Science and Technology of China
摘 要:1D europium coordination polymer wires were successfully prepared by reacting europium chloride with tributyl phosphate(TBP) at 160 oC for 12 h. The products were characterized by XRD,IR,TG,DTA,SEM,and EDS. SEM results showed that the wires were with diameters ranging from several hundreds of nanometers to ~5 μm and lengths going up to several hundreds of micrometers. Influencing factors such as the dosage of reactants and reaction time on the preparation were systematically investigated. Strong emission centering at 590 nm was realized in the coordination polymer wires on excitation at 395 nm.
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