经氰化处理的黄铜矿和方铅矿的浮选行为与机理

来源期刊:中国有色金属学报(英文版)2016年第12期

论文作者:马艺闻 韩跃新 朱一民 李艳军 刘浩

文章页码:3245 - 3252

关键词:黄铜矿;方铅矿;氰化吸附;浮选;丁基黄药

Key words:chalcopyrite; galena; cyanide absorption; flotation; butyl xanthate

摘    要:研究了CN-与黄铜矿和方铅矿之间的吸附作用,然后在丁基黄药(BX)体系下研究了氰化吸附后的黄铜矿、方铅矿的浮选试验。结果表明,CN-与两种矿物表面存在化学吸附作用,并可用Langmuir等温模型近似描述。在pH值为6.5,丁基黄药用量为4.0 mg/L的适宜条件下,氰化后的黄铜矿和方铅矿的浮选回收率可分别达到82.1%和63.9%。尽管CN-降低了黄铜矿、方铅矿表面的接触角,但丁基黄药能够提高氰化矿物表面的疏水性。CN-对黄铜矿的抑制作用大于方铅矿。在pH值为4.2~8.4时,BX与氰化后的方铅矿表面的相互作用存在静电吸附;BX在氰化后的黄铜矿表面的吸附作用为化学吸附。

Abstract: Adsorbing tests between CN- and chalcopyrite or galena were conducted firstly, and then flotation tests of the two cyaniding minerals were investigated in butyl xanthate (BX) system. Results showed that the interaction between CN- and the two mineral surfaces were both chemical adsorption and can be described by the Langmuir adsorption isotherm model. In the optimum condition of pH 6.5 and 4.0 mg/L BX, the recovery of cyaniding chalcopyrite and galena reached 82.1% and 63.9%, respectively. BX improved the hydrophobicity of the surfaces of the two minerals, although CN- reduced the contact angle on the surface of minerals. The inhibitory effect of CN- on chalcopyrite far outweighed galena. Electrostatic adsorption exists in the interaction between BX and the surface of galena after cyanide treatment in the pH range of 4.2-8.4, while the interactions between BX and the surface of chalcopyrite after cyanide treatment is chemical adsorption.

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