Degradation of solid oxide electrolysis cells: Phenomena,mechanisms, and emerging mitigation strategies——A review
来源期刊：JOURNAL OF MATERIALS SCIENCE TECHNOLOG2020年第20期
论文作者：Yi Wang Wenyuan Li Liang Ma Wei Li Xingbo Liu
文章页码：35 - 55
摘 要：Solid oxide electrolysis cell（SOEC） is a promising electrochemical device with high efficiency for energy storage and conversion.However,the degradation of SOEC is a significant barrier to commercial viability.In this review paper,the typical degradation phenomena of SOEC are summarized,with great attention into the anodes/oxygen electrodes,including the commonly used and newly developed anode materials.Meanwhile,mechanistic investigations on the electrode/electrolyte interfaces are provided to unveil how the intrinsic factor,oxygen partial pressure pO2,and the electrochemical operation conditions,affect the interracial stability of SOEC.At last,this paper also presents some emerging mitigation strategies to circumvent long-term degradation,which include novel infiltration method,development of new anode materials and engineering of the microstructure.
Yi Wang1，Wenyuan Li1，Liang Ma1,2，Wei Li1，Xingbo Liu1
1. Department of Mechanical & Aerospace Engineering, West Virginia University2. School of Materials Science and Engineering, Hebei University of Engineering
摘 要：Solid oxide electrolysis cell（SOEC） is a promising electrochemical device with high efficiency for energy storage and conversion.However,the degradation of SOEC is a significant barrier to commercial viability.In this review paper,the typical degradation phenomena of SOEC are summarized,with great attention into the anodes/oxygen electrodes,including the commonly used and newly developed anode materials.Meanwhile,mechanistic investigations on the electrode/electrolyte interfaces are provided to unveil how the intrinsic factor,oxygen partial pressure pO2,and the electrochemical operation conditions,affect the interracial stability of SOEC.At last,this paper also presents some emerging mitigation strategies to circumvent long-term degradation,which include novel infiltration method,development of new anode materials and engineering of the microstructure.
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