Kinetics of Liquid-Phase Hydrogenation of Toluene Catalyzed by Hydrogen Storage Alloy MlNi5
来源期刊：JOURNAL OF RARE EARTHS2004年第3期
论文作者：徐国华 安越 陈长聘 袁华军
Key words：hydrogen storage alloys; kinetics; toluene; liquid-phase hydrogenation; rare earths;
Abstract: The kinetics of liquid-phase hydrogenation of toluene catalyzed by MlNi5 was studied by investigating the influences of the reaction temperature and pressure on the mass transfer-reaction processes inside the slurry. The results show that the reaction rate accelerates when the reaction temperature increases, and reaches its maximum at about 490 K, but if temperature is higher than 510 K, the reaction rate decreases rapidly. The whole reaction process is controlled by the reaction at the surface of the catalyst particles. The mass transfer resistance at gas-liquid interface and that from the bulk liquid phase to the surface of the catalyst particle can be neglected. The apparent reaction rate is zero order for toluene concentration and first order for hydrogen concentration in the liquid phase. The kinetic model is obtained. The kinetic model fits the experimental data very well. The apparent activation energy of the hydrogen absorption reaction of MlNi5-toluene slurry system is 41.01 kJ·mol-1.
徐国华1，安越1，陈长聘1，袁华军1
(1.College of Materials Science & Chemical Engineering, Zhejiang University, Hangzhou 310027, China)
Abstract:The kinetics of liquid-phase hydrogenation of toluene catalyzed by MlNi5 was studied by investigating the influences of the reaction temperature and pressure on the mass transfer-reaction processes inside the slurry. The results show that the reaction rate accelerates when the reaction temperature increases, and reaches its maximum at about 490 K, but if temperature is higher than 510 K, the reaction rate decreases rapidly. The whole reaction process is controlled by the reaction at the surface of the catalyst particles. The mass transfer resistance at gas-liquid interface and that from the bulk liquid phase to the surface of the catalyst particle can be neglected. The apparent reaction rate is zero order for toluene concentration and first order for hydrogen concentration in the liquid phase. The kinetic model is obtained. The kinetic model fits the experimental data very well. The apparent activation energy of the hydrogen absorption reaction of MlNi5-toluene slurry system is 41.01 kJ·mol-1.
Key words:hydrogen storage alloys; kinetics; toluene; liquid-phase hydrogenation; rare earths;
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