Influence of Temperature on Sulfate Attack of Limestone Filler Cement Mortar

来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2006年第S1期

论文作者：高小建

文章页码：80 - 85

摘    要：<正>Mortar prisms were made with three different cementitious materials （with or without mineral admixture） plus 30% mass of limestone filler. After 28 days of curing in water at room temperature, the mortars were submerged in 2% magnesium sulfate solution at different temperatures （5℃, 20℃and alternate temperature between 5℃and 20℃） for a year. The appearance and strength development were measured on these immersed prisms at intervals, and samples selected from the surface of prisms were examined by X-ray diffraction （XRD） and Fourier transform infrared spectroscopy （FTIR）. The results show that the influence of temperature on the resistance to sulfate attack of mortar is related to the binder compositions. A higher temperature leads to a quicker strength loss and appearance deterioration of the mortar without mineral admixture. For blended cements, a higher temperature is favorable for the pozzolanic reaction of mineral admixture and the overall deterioration of mortar is reduced with the increasing temperature. When the mineral admixture has a lower reactivity, such influence of temperature on the resistance to sulfate attack of mortar containing admixtures becomes greater. At the three different solution temperatures, two blended cements show significantly improved resistances to sulfate attack. After 1 year of exposure to magnesium sulfate solutions, the formation of thaumasite was checked in the OPC mortars at both 5℃and 20℃. It is concluded that the thaumasite formation is not limited to structures at low temperature （less than 15℃）.