Cerium Oxide Film Prepared from Molten Salts
来源期刊:稀有金属2001年第2期
论文作者:刘正义 匡同春 白晓军 成晓玲
摘 要:Cerium oxide film formed on the nickel electrode at 453 K in LiNO3-KNO3 molten salts. The molten salt back ground and the cathode process of Leeds on the nickel electrode were studied by using cyclic voltammetry. The cathodic reaction mechanism of the molten salt background was: O2+e O22; O2+2NO-3 → 2NO2+2O2. According to the results of SEM and XPS, cerium oxide film, which is composed of CeO2, can form on the nickel electrode at - 1.850 V vs. Ag/AgNO3 (0.1 mol/L) reference electrode.
刘正义1,匡同春2,白晓军2,成晓玲2
(1.华南理工大学机械电子工程系,广州 510641;
2.广东工业大学实验研究中心,广州 510090)
摘要:Cerium oxide film formed on the nickel electrode at 453 K in LiNO3-KNO3 molten salts. The molten salt back ground and the cathode process of Leeds on the nickel electrode were studied by using cyclic voltammetry. The cathodic reaction mechanism of the molten salt background was: O2+e O22; O2+2NO-3 → 2NO2+2O2. According to the results of SEM and XPS, cerium oxide film, which is composed of CeO2, can form on the nickel electrode at - 1.850 V vs. Ag/AgNO3 (0.1 mol/L) reference electrode.
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