Synthesis and Swelling Behaviors of Microcrystal Muscovite Composite Superabsorbent by Photopolymerization
来源期刊：Journal Of Wuhan University Of Technology Materials Science Edition2016年第1期
论文作者：万涛 LIAO Ling HUANG Runqiu WU Daqing Tang Li XIONG Jing CHEN Qiaohe
文章页码：151 - 156
摘 要：A new microcrystal muscovite composite superabsorbent was synthesized by UV photopolymerization using 2-hydroxy-2-methylpropiophenone（1 173） as photoinitiator,N,N-methylene bisacrylamide（MBA） as crosslinker,acrylic acid（AA）,acrylamide（AM） and sodium 4-styrenesulfonate（SSS） as comonomers.Factors affecting water and salt absorption of the microcrystal muscovite composite superabsorbent,such as crosslinker amount,microcrystal muscovite concentration,photoinitiator content,and SSS concentration,were systematically studied.Water retention capacity of the composite superabsorbent was also investigated.The results show that microcrystal muscovite composite superabsorbent has water absorbency of 550 g/g,salt absorbency of 62 g/g,and water retention of 60% after heating at 70 ℃ for 40 h.The microcrystal muscovite is physically combined into the polymeric network without destroying its polycrystalline structure and the surface of the microcrystal muscovite composite superabsorbent has some deep and small holes.
万涛1,2，LIAO Ling2，HUANG Runqiu1，WU Daqing3，Tang Li2，XIONG Jing2，CHEN Qiaohe2
1. State Key Lab of Geohazard Prevention & Geoenvironment Protection,Chengdu University of Technology2. Mineral Resources Chemistry Key Laboratory of Sichuan Higher Education Institutions,Chengdu University of Technology3. Petro China Sichuan Petrochemical Co.,Ltd
摘 要：A new microcrystal muscovite composite superabsorbent was synthesized by UV photopolymerization using 2-hydroxy-2-methylpropiophenone（1 173） as photoinitiator,N,N-methylene bisacrylamide（MBA） as crosslinker,acrylic acid（AA）,acrylamide（AM） and sodium 4-styrenesulfonate（SSS） as comonomers.Factors affecting water and salt absorption of the microcrystal muscovite composite superabsorbent,such as crosslinker amount,microcrystal muscovite concentration,photoinitiator content,and SSS concentration,were systematically studied.Water retention capacity of the composite superabsorbent was also investigated.The results show that microcrystal muscovite composite superabsorbent has water absorbency of 550 g/g,salt absorbency of 62 g/g,and water retention of 60% after heating at 70 ℃ for 40 h.The microcrystal muscovite is physically combined into the polymeric network without destroying its polycrystalline structure and the surface of the microcrystal muscovite composite superabsorbent has some deep and small holes.
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