Preparation and Luminescence Properties of Y2O3:Eu3+ Nanorods via Post Annealing Process
来源期刊：Journal of Rare Earths2006年第S1期
论文作者：徐珍秀 洪樟连 赵起超 彭丽霞 张朋越
文章页码：111 - 114
摘 要：<正>Yttrium oxide doped with europium has a great prospective for FED and PDP phosphor application. In present study, the precursor of yttrium oxide hydroxide nitrate nanorod, which was prepared via hydrotherma] reaction route using PEG-6000 as template from the starting Y（NO3）3 and KOH reactant system, was used to prepare Y2O3:Eu3 + nanorod via a post annealing process during which the precursor with adjustable shape and size was transformed to final Y2O3: Eu3 + product. XRD, field emission scanning electron microscopy （FE-SEM） and photoluminescence spectra （PL） were used to characterize the crystalline, morphology and luminescence properties of as-formed Y2O3: Eu3+ products synthesized at different post annealing temperatures, respectively. The results indicate that. grain morphology of obtained Y2O3:Eu3+ product was nanorod with a mean diameter of about 40 60 nm and length of about 500 700 nm, the nanorod structure and morphology of obtained Y2O3: Eu + product maintained during post annealing process and the size varied slightly with different annealing temperatures. Pure cubic Y2O3:Eu3 + phase was formed and the size was the smallest at annealing treatment of 500℃. Under the annealing temperature below 500℃its diameter increased with increasing annealing temperature , and remained in a stable size when the annealing temperature was above 500℃. The PL spectra of excitation spectra of Y2O3:Eu3+ product show that it exhibits excitation band located at about 395 and 468 nm, respectively. Above two excitation bands could be ascribed to the transition 4f-4f of Eu3+ ions in the Y2O3 host. On the other hand, the main emission peaks of the as-prepared products could be ascribed to the Eu3 + ions transition from 5D0 to 7F2. Furthermore, the luminescent intensity was improved about three times when the annealing temperature increased from 500 to 1000℃.
徐珍秀，洪樟连，赵起超，彭丽霞，张朋越
摘 要：<正>Yttrium oxide doped with europium has a great prospective for FED and PDP phosphor application. In present study, the precursor of yttrium oxide hydroxide nitrate nanorod, which was prepared via hydrotherma] reaction route using PEG-6000 as template from the starting Y（NO3）3 and KOH reactant system, was used to prepare Y2O3:Eu3 + nanorod via a post annealing process during which the precursor with adjustable shape and size was transformed to final Y2O3: Eu3 + product. XRD, field emission scanning electron microscopy （FE-SEM） and photoluminescence spectra （PL） were used to characterize the crystalline, morphology and luminescence properties of as-formed Y2O3: Eu3+ products synthesized at different post annealing temperatures, respectively. The results indicate that. grain morphology of obtained Y2O3:Eu3+ product was nanorod with a mean diameter of about 40 60 nm and length of about 500 700 nm, the nanorod structure and morphology of obtained Y2O3: Eu + product maintained during post annealing process and the size varied slightly with different annealing temperatures. Pure cubic Y2O3:Eu3 + phase was formed and the size was the smallest at annealing treatment of 500℃. Under the annealing temperature below 500℃its diameter increased with increasing annealing temperature , and remained in a stable size when the annealing temperature was above 500℃. The PL spectra of excitation spectra of Y2O3:Eu3+ product show that it exhibits excitation band located at about 395 and 468 nm, respectively. Above two excitation bands could be ascribed to the transition 4f-4f of Eu3+ ions in the Y2O3 host. On the other hand, the main emission peaks of the as-prepared products could be ascribed to the Eu3 + ions transition from 5D0 to 7F2. Furthermore, the luminescent intensity was improved about three times when the annealing temperature increased from 500 to 1000℃.
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