Size dependent optical properties of LaB6 nanoparticles enhanced by localized surface plasmon resonance
来源期刊：JOURNAL OF RARE EARTHS2013年第11期
论文作者：洪源 张晓松 李波 李梦真 石庆良 王有为 李岚
文章页码：1096 - 1101
摘 要：Lanthanum hexaboride nanoparticles,with high emission electrons in cathode materials and peculiar blocking near infrared wavelengths,were applied for many aspects.Based on the quasi-static approximation of Mie theory,the size dependent optical properties of LaB6nanoparticles were researched,such as refractive index n（ω）,extinction coefficient k（ω）,reflectivity R（ω）,absorption coefficientα（ω）,and electron energy loss L（ω）.Due to the localized surface plasmon resonance（LSPR）,the extinction coefficient k（ω）and absorption coefficientα（ω）depended on the size,and the LSPR peaks red-shifted with sizes increased,which was different from that of bulk materials.In addition,electron energy-loss spectrum L（ω）showed electrons oscillation reinforced,since electrons absorbed the photon energy and generated resonance.Further,reflectivity R（ω）and refractive index n（ω）indicated that the light in near infrared region could not be propagated on the surface of LaB6materials,which exhibited metallic behaviors.So the resonance peak of LaB6nanoparticle was located in near-infrared region,making use of this property for solar control glazing and heat-shielding application.
洪源，张晓松，李波，李梦真，石庆良，王有为，李岚
Institute of Material Physics, Key Laboratory of Display Materials and Photoelectric Devices, Ministry of Education, Tianjin University of Technology
摘 要：Lanthanum hexaboride nanoparticles,with high emission electrons in cathode materials and peculiar blocking near infrared wavelengths,were applied for many aspects.Based on the quasi-static approximation of Mie theory,the size dependent optical properties of LaB6nanoparticles were researched,such as refractive index n（ω）,extinction coefficient k（ω）,reflectivity R（ω）,absorption coefficientα（ω）,and electron energy loss L（ω）.Due to the localized surface plasmon resonance（LSPR）,the extinction coefficient k（ω）and absorption coefficientα（ω）depended on the size,and the LSPR peaks red-shifted with sizes increased,which was different from that of bulk materials.In addition,electron energy-loss spectrum L（ω）showed electrons oscillation reinforced,since electrons absorbed the photon energy and generated resonance.Further,reflectivity R（ω）and refractive index n（ω）indicated that the light in near infrared region could not be propagated on the surface of LaB6materials,which exhibited metallic behaviors.So the resonance peak of LaB6nanoparticle was located in near-infrared region,making use of this property for solar control glazing and heat-shielding application.
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