Removal Mechanism of Aqueous Lead by a Novel Eco-material: Carbonate Hydroxyapatite

Huanyan XU, Lei YANG, Peng WANG, Yu LIW and Mingsheng PENG School of Materials Science and Engineering, Harbin University of Science and Technology, Harbin 150040, China School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430073, China Department of Earth Sciences, Zhongshan University, Guangzhou 510275, China

摘 要：<正>Kinetics and mechanisms on the removal of aqueous lead ion by carbonate hydroxyapatite （CHap） are investigated in the present work. Experimental results show that, in the whole pH range, the lead removal percentage increases with decreasing pH values and reaches a maximum at pH=2-3. Under some conditions, the lead residual concentration is below national integrated wastewater discharge standard, even drinking water standard. The removal behavior is a complicated non-homogeneous solid/liquid reaction, which can be described by two stages from kinetic point of view. At the earlier stage, reaction rate is so fast that its kinetic course is intricate, which requires further study. At the latter stage, the rate of reaction becomes slow and the process of reaction accords with one order reaction kinetic equation. Experimental results show that the relationship between reaction rate constant k1 and temperature T accords to Arrhenius Equation, and the activation energy of sorption （Ea） is 11.93 kJ/mol and frequency factor （A） is 2.51 s-1. X-ray diffraction （XRD）, scanning electron microscopy with an energy dispersive X-ray fluoresence spectrometer （SEM-EDS） and toxicity characteristic leaching procedure （TCLP） test were conducted in this work. It is indicated that the main mechanism is dissolution-precipitation, accompanying with superficial sorption.

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