Synthesis and Crystal Structure of Binuclear Ytterbium Complex with Isonicotinoyl Hydrazone
来源期刊：JOURNAL OF RARE EARTHS2001年第2期
论文作者：卜显和 张若桦 鹿守亮 陈巍
Abstract: The ytterbium complex of isonicotinoyl hydrazone was synthesized and the structure was determined by X-ray diffraction analysis. The crystal and molecular structure of the title complex ［Yb2(L)3］(OH)3 shows that the complex has two identical nine-coordinated ytterbium ions with each surrounded by N3O6 donor set. Two ytterbium ions are bridged by three phenolate oxygen atoms. The geometry around each ytterbium ions can be considered as a three-capped trigonal prism.
卜显和1，张若桦3，鹿守亮4，陈巍3
(1.Department of Chemistry, Nankai University;
2.lThe State Key Laboratory on Rare Earth Materials Chemistry and Applications, Peking University,;
3.Department of Chemistry, Nankai University,;
4.. Department of Chemistry, Nankai University,)
Abstract:The ytterbium complex of isonicotinoyl hydrazone was synthesized and the structure was determined by X-ray diffraction analysis. The crystal and molecular structure of the title complex ［Yb2(L)3］(OH)3 shows that the complex has two identical nine-coordinated ytterbium ions with each surrounded by N3O6 donor set. Two ytterbium ions are bridged by three phenolate oxygen atoms. The geometry around each ytterbium ions can be considered as a three-capped trigonal prism.
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