Granulation of primary dendritic TiC in TiC/Ti composite
来源期刊：中国有色金属学报(英文版)2003年第z1期
论文作者：JIN Yun-xue (金云学) ZENG Song-yan (曾松岩) ZHANG Cheng-jun (张成军)
文章页码：89 - 93
Key words：Ti alloy; composite; mechanism of granulation; high temperature heat treatment
Abstract: Samples, made of Ti-6Al-2C alloy through casting, were held at 1300℃ for a relatively long period and their coarse primary grain became granular, which may contribute to the mechanical properties of the alloy. The mechanism of the granulation of primary dendritic TiC was studied by means of XRD, SEM and TEM. The results show that the granulation is carried out through the process of dissolution, diffusion and precipitation of carbon, and the dominant step is diffusion. The equilibrium compositions are different at the points with different curvatures according to Gibbs-Thomson effect. This equilibrium is broken down by the diffusion of carbon at high temperatures, which makes the TiC dissolve at the point with high degree of curvature and precipitate at the point with low degree of curvature. Eventually, the dendrite is molten completely at the point with high degree of curvature so that it becomes several granular grains.
JIN Yun-xue (金云学)1,2, ZENG Song-yan (曾松岩)1, ZHANG Cheng-jun (张成军)1,2
(1. School of Materials Science and Engineering,
Harbin Institute of Technology, Harbin 150001, China;
2. College of Material Engineering, Jiamusi University, Jiamusi 154007, China)
Abstract:Samples, made of Ti-6Al-2C alloy through casting, were held at 1300℃ for a relatively long period and their coarse primary grain became granular, which may contribute to the mechanical properties of the alloy. The mechanism of the granulation of primary dendritic TiC was studied by means of XRD, SEM and TEM. The results show that the granulation is carried out through the process of dissolution, diffusion and precipitation of carbon, and the dominant step is diffusion. The equilibrium compositions are different at the points with different curvatures according to Gibbs-Thomson effect. This equilibrium is broken down by the diffusion of carbon at high temperatures, which makes the TiC dissolve at the point with high degree of curvature and precipitate at the point with low degree of curvature. Eventually, the dendrite is molten completely at the point with high degree of curvature so that it becomes several granular grains.
Key words:Ti alloy; composite; mechanism of granulation; high temperature heat treatment
