Synthesis and Crystal Structure of a Novel Ion-pair Complex of [Li（THF）4Nd（C8H8）2]·2THF
来源期刊：Journal of Rare Earths1992年第4期
论文作者：齐贵中 林永华 金松春 沈琪
文章页码：263 - 266
摘 要：<正> The reaction of NdCl3 with lithium methylnaphthalene in 1:2 mole ratio in THF generates black powder.The powder reacts with cyclooctatetraene（COT）in THF to form the title complex.[Li（THF）4Nd（C8H8）2]·2THF crystallizes in the monoclinic space group P2/c with unit-cell dimensions a=1.7858（7）nm,h=1.3243（4）nm,c=1.8086（6）nm.β=106.52（4）°,V=4.10 nm3 and Dc=1.268 g/cm3 for Z=4.F（000）=1660,R=0.0774,Rn=0.0733.The complex consists of discrete ion-pair and two THF moleculesadduct.In the anion,the neodymium atom is coordinated by two COT rings.The structure of the cation showsthat the lithium atom is attached with THF molecules only.
齐贵中，林永华，金松春，沈琪
摘 要：<正> The reaction of NdCl3 with lithium methylnaphthalene in 1:2 mole ratio in THF generates black powder.The powder reacts with cyclooctatetraene（COT）in THF to form the title complex.[Li（THF）4Nd（C8H8）2]·2THF crystallizes in the monoclinic space group P2/c with unit-cell dimensions a=1.7858（7）nm,h=1.3243（4）nm,c=1.8086（6）nm.β=106.52（4）°,V=4.10 nm3 and Dc=1.268 g/cm3 for Z=4.F（000）=1660,R=0.0774,Rn=0.0733.The complex consists of discrete ion-pair and two THF moleculesadduct.In the anion,the neodymium atom is coordinated by two COT rings.The structure of the cation showsthat the lithium atom is attached with THF molecules only.
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