Investigation of the red-shift of the emission of microwave solvothermally-grown europium doped calcium sulphide crystals
来源期刊：Journal of Rare Earths2014年第8期
论文作者：董晓菲 陆启飞 卢志娟 毛智勇 王达健
文章页码：702 - 708
摘 要：A distinct red-shift to 660 nm-featured longer wavelength of europium doped calcium sulphide nanocrystals was observed in a microwave（MW）-assisted solvothermal synthesis procedure. This red-shift was probably due to a combined effect from Mg2+ codoping and strain accumulation at grain boundaries. The latter originated from the formation of small grains with an average size of around 200 nm in micrometer sized crystals upon Mg2+ codoping. In particular, MW electromagnetic field suppressed grain growth and enabled a reconstruction of atoms at the inner grain boundary at which the field strength was intensified around rare earth ions in host lattices. This MW synthesis route provided an option to prepare luminescent crystals with the desired blue-excitable longer wavelength emission.
董晓菲，陆启飞，卢志娟，毛智勇，王达健
Institute of Materials Physics, School of Materials Science and Engineering, Tianjin University of Technology
摘 要：A distinct red-shift to 660 nm-featured longer wavelength of europium doped calcium sulphide nanocrystals was observed in a microwave（MW）-assisted solvothermal synthesis procedure. This red-shift was probably due to a combined effect from Mg2+ codoping and strain accumulation at grain boundaries. The latter originated from the formation of small grains with an average size of around 200 nm in micrometer sized crystals upon Mg2+ codoping. In particular, MW electromagnetic field suppressed grain growth and enabled a reconstruction of atoms at the inner grain boundary at which the field strength was intensified around rare earth ions in host lattices. This MW synthesis route provided an option to prepare luminescent crystals with the desired blue-excitable longer wavelength emission.
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