Surface chemistry of activation of lime-depressed pyrite in flotation
来源期刊：中国有色金属学报(英文版)2000年第6期
论文作者：胡岳华 章顺力 邱冠周 J.D.Miller
文章页码：798 - 803
Key words：pyrite; surface chemistry; activation flotation
Abstract: The depression of pyrite by lime is attributed to the surface formation of Ca(OH)2, CaSO4 and Fe(OH)3 as determined by XPS analysis. Xanthate flotation tests show that oxalic acid and other organic acids, as well as sulphuric acid and other inorganic acids and their salts can restore xanthate flotation of pyrite after depression by lime. In terms of XPS analysis, solution chemistry calculations and electrochemical measurements, it is evident that these chemicals act as activators to reduce pulp pH, prevent further oxidation of pyrite, and dissolve surface calcium or iron species to create a fresh surface. Activation efficiency was quantitatively discussed based on an activation index related to the polar group functionality of the activators. The results for activation flotation of pyrite are very well explained using the activation index. Oxalic acid which exhibited the greatest activation index can be substituted for sulfuric acid, which may solve poten- tial environmental and maintenance problems associated with calcification/scaling reaction expected with sulfuric acid.
