Reactivity of Nanostructured MnO2 in Alkaline Medium Studied with a Microcavity Electrode: Effect of Oxidizing Agent
来源期刊：JOURNAL OF MATERIALS SCIENCE TECHNOLOG2011年第7期
论文作者：L.Benhaddad K.Rahmouni H.Takenouti
文章页码：585 - 593
摘 要：The synthesis of MnO2 powders by hydrothermal method with different oxidizing agents has been successfully achieved. The characterizations by scanning electron microscopy, energy-dispersive X-ray analyses, transmission electron microscopy, and X-ray diffraction techniques confirm the synthesis of nanostructured γ-MnO2 powders. The electrochemical reactivity of these powders in 1 mol/l KOH is investigated by cyclic voltammetry and electrochemical impedance spectroscopy （EIS） by using microcavity electrode. The results reveal that the MnO2 synthesized with Na2S2O8 shows the highest electrochemical reactivity in the test medium. This is due both to its large expanded surface area and its crystallographic variety γ-MnO2 formed in the matrix of ramsdellite, which is largely used as cathodic material for primary batteries. However, the presence of pyrolusite in the structure of γ-MnO2 synthesized with （NH4）2S2O8 decreases its electrochemical reactivity due to its narrow 1×1 size tunnel, which hinders the protons insertion.
L.Benhaddad1,2，K.Rahmouni3，H.Takenouti3
2. UPR 15 du CNRS LISE-Laboratoire Interfaces et Systèmes Electrochimiques , UPMC University Paris 06,Case 133, 4 place Jussieu, 75252 Paris Cedex 05, France3. UPR 15 du CNRS LISE-Laboratoire Interfaces et Systèmes Electrochimiques,UPMC University Paris 06,Case 133,4 place Jussieu, 75252 Paris Cedex 05,France
摘 要：The synthesis of MnO2 powders by hydrothermal method with different oxidizing agents has been successfully achieved. The characterizations by scanning electron microscopy, energy-dispersive X-ray analyses, transmission electron microscopy, and X-ray diffraction techniques confirm the synthesis of nanostructured γ-MnO2 powders. The electrochemical reactivity of these powders in 1 mol/l KOH is investigated by cyclic voltammetry and electrochemical impedance spectroscopy （EIS） by using microcavity electrode. The results reveal that the MnO2 synthesized with Na2S2O8 shows the highest electrochemical reactivity in the test medium. This is due both to its large expanded surface area and its crystallographic variety γ-MnO2 formed in the matrix of ramsdellite, which is largely used as cathodic material for primary batteries. However, the presence of pyrolusite in the structure of γ-MnO2 synthesized with （NH4）2S2O8 decreases its electrochemical reactivity due to its narrow 1×1 size tunnel, which hinders the protons insertion.
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